42CrMo钢NiWP化学镀镀液稳定性及镀层性能分析.docx

摘要 摘 要 - - I - 本文对 42CrMo 钢合金的预处理、化学镀液的基本配方、化学镀工艺、镀液成份对镀 液稳定及镀层质量的影响做了系统的研究。通过正交实验得到在 42CrMo 钢表面制备 Ni-W-P 合金镀层的最优配方工艺，并对影响镀液稳定性的三种因素即：pH 值、温度、络 合剂进行了 PdCl2 滴定和 EDTA2Na 标准液滴定的稳定性测试并对镀层耐磨性、耐蚀性、模 拟煤矿条件下腐蚀磨损性进行实验，分析镀层的组织结构、成份、形貌为化学镀的工业应 用提供可靠依据。 实验结果表明， Ni-W-P 合金镀层均为表面光洁致密、结构 均匀的混晶态镀 层 。 Ni-W-P 化学镀在 pH 为 8.0、温度 85℃下施镀的镀液为最稳定镀液且合金镀层的耐 蚀、耐磨性能 是基体的 2.68 倍，耐酸腐蚀性能是基体的 1365.58 倍，在 15%煤水 混合 液中镀件 的耐腐 蚀磨 损性是基 体的 1.33 倍 ，在 25%煤水 混合液 中镀件的 耐腐蚀 磨损 性是基体 的 1.72 倍， 35%煤水 混合 液中镀 件的耐腐 蚀磨损 性是 基体的 2 倍。 关键词：42CrMo 钢；化学镀 Ni-W-P；镀液 稳定性；耐 腐蚀磨 损 性 ；镀液稳 定性 A Abstract - - II - In this paper, the 42CrMo steel alloy pretreatment, chemical plating solution of the basic formula, chemical plating process, the solution components of plating solution stability and coating quality effect of system research. Through the orthogonal experiment to get in 42CrMo steel surface preparation Ni-W-P alloy coating the optimal technics, and influence the stability of the solution of three kinds of factors：pH、temperature and complexed agent to the PdCl2 titration and EDTA2Na standard droplet fixed stability test and the coating wear resistance, corrosion resistance, simulated coal mine under the conditions of corrosion wear resistance experiment. Analysis of the coating structure, composition, morphology for chemical plating industrial application to provide reliable basis. The experimental results show that: Ni-W-P alloy coating are smooth surface density, uniform structure mix crystalline plating. Ni-W-P chemical plating at pH 8.0, temperature 85 ℃ was under the plating solution for the most stable solution and alloy coating corrosion resistance, Plating pieces of wearability is 2.68 times of the matrix. Plating pieces of acid corrosive sex is 1365.58 times of the matrix. In 15% of coal water mixture of plating pieces of corrosion wear resistance is 1.33 times that of The Times the matrix; In 25% of coal water mixture of plating pieces of corrosion wear resistance is 1.72 times that of The Times the matrix,in 35% o