稀土掺杂氟化物上转换发光粉的制备及光谱性能研究.docVIP

河北联合大学轻工学院 QINGGONG COLLEGE, HEBEI UNITED UNIVERSITY 论文题目：稀土掺杂氟化物上转换发光粉的制备及 光谱性能研究 学生姓名 赵智阳 学 号：200915010115 专业班级：09材料化学1班 学 部：材料化工部 指导教师：廉志红教授 2013年5月31日 上转换发光材料能够将人眼看不见的红外光转变为可见光，这一特性使得它 们在上转换激光器、三维立体显示、防伪识别、红外探测、生物检测等诸多领域 都具有广阔的应用前。本文采用罔和反应法合成丫对980nm响应的NaYF4： Er3+, Yb3+上转换发光粉体，釆用XRD、STM、TEM及荧光光谱分析等手段表征样品。 结果表明，采用同相反应法制备六方相NaYF4: Er3+, Yb3+(p- NaYF4： Er3+, Yb3+)粉体，最佳工艺参数是采用双坩埚、添加NH4HF2作为保护气氛，在630°C 下，烧结5h。光谱分析表叨，NaYF4： Er3+, Yb3+在980nm激发卜有5个发光峰， 分别位于 380、409、526、540 和 652nm,分别对应于 Er3+的 4Gu/2-4I15/2、 2H9/2―4Il5/2、2Hii/2—4Il5/2 4S3/2—4Il5/2 和 4F9/2^4Il5/2 跃迁。 关键词固相反应法；氟化物；上转换发光材料；光谱特性 Abstract Up conversion luminescence materials possess the excellent property of converting the invisible infrared light to visible light, therefore, they have wide applications in the field of up conversion laser, 3-D display，anti-counterfeiting， infrared detection, bio-detection, and so on. The fluoride up conversion materials NaYF4：Er3+, Yb3+, Which is sensitive to 980nm respectively, was synthesized by the solid reaction method. XRD，STM，TEM and the up conversion spectra analysis were employed to characterize the samples. The optimum technological parameters of synthesis hexagonal p-phase NaYF4： Ei，3+，Yb3+ powders by solid reaction method were described as the following. Double-crucible method, adding NH4HF2 as shielding gas atmosphere. The calcine temperature and time of the powders were 61D for 5 hours ，respectively. And the particle diameters of NaYF4:Er3+, Yb3+. There were five emission bands in the up conversion emission spectra of NaYF*4:Er3+, Yb3+ excited by the 980nm LD, which peak at 380nm，409nm，526nm and 652nm. And they were corresponded to the 4Gii/2—4Ii5/2、2H9/2—?4Ii5/2、2氏 5/2、4S3/2―4I i5/2 and ￥9/2一%5/2 transitions of Er cations. Keywords solid reaction method ; fluorides ； up conversion luminescence material ； spectrum properties 目 录 TOC \o 1-5 \h \z x 1 论文题目：稀土掺杂氟化物上转换发光粉的制备及 1 光谱性能研究 1 学生姓名：赵智阳 1 学 号：200915010115 1 2013年5月31日 1 2 HYPERLINK \l bookmark1 \o Curren