纺丝方式对丝素蛋白构象转变及性能影响的研究-材料工程专业论文.docx

浙江理工大学硕士学位论文不同 浙江理工大学硕士学位论文 不同纺丝方式对丝素蛋白构象转变影响的研究 万方数据 万方数据 维中无规线团、α 螺旋、β 折叠、β 转角的含量，并分析其误差。结果显示离心纺丝制备的 丝素纤维中 β 折叠的含量要比静电纺丝制备的丝素纤维要高 10%左右，并且通过二次导数 谱得到的拟合结果约有 10%的相对误差。 关键词：再生丝素；静电纺丝；离心纺丝；纳米纤维；性能；二级结构 II A comparative study of the conformational transtitions of silk fibroin produced by different spinning processes Abstract Rencent years, the regernerated silk fibroin nanofibers are widely used in the biomaterial field due to its high surface area and excellent biocompatibility. Electrospinning is the most popular technique to produce regernerated silk fibroin nanofibers. The diameter of the regernerated silk fibroin nanofibers is usually under 100nm, but the poor mechanical property and low rate limits its industrialization. Therefore, a new method is need to produced regernerated silk fibroin nanofibers. Centrifugal spinning , a new method, developed in recent years. This paper produced the regernerated silk fibroin nanofibers using the self made centrifugal spinning device, and specifically to study the effect of concentration, spinneret rotational speed, needle diameter, spinning distance on fiber morphology and diameter. 20% concentration, 8000rpm spinneret rotational speed, 30G needle diameter and 12cm spinning distance is the best condition. Mechanical properties of silk fibroin nanofibers is largely determined by the secondary structure of silk fibroin. To study the effect of electrospinning and centrifugal spinning process on the mechanical properties of regernerated silk fibroin nanofibers, this paper uses scanning electron microscopy, infrared spectroscopy, X-ray diffraction, far infrared spectroscopy, differential scanning calorimetry thermal analysis, thermal analysis and polarized light microscopy to analysis the surface morphology, structure, thermal performance and degree of orientation. Study the effect of the mechanism of the two spinning process on the surface morphology, structure, thermal performance and degree of orientation. Bending instability