《溴甲烷甲基化苯制备对二甲苯的研究》-毕业论文（设计）.doc

毕业设计(论文) 论文题目： 溴甲烷甲基化苯制备 对二甲苯的研究 学生姓名： 学生学号： 专业班级： 学院名称： 化学化工学院 指导老师： 教授 学院院长： 教授 2011年6月7日 溴甲烷甲基化苯制备对二甲苯 摘 要 对二甲苯是一种重要的石油化工基础原料，主要用于制取对苯二甲酸和对苯二甲酸二甲酯，进而生产聚酯。在HZSM-5分子筛上，甲苯甲醇烷基化选择性合成对二甲苯的工艺已被广泛研究，但溴甲烷甲基化苯制备对二甲苯的反应少有报道。 本论文对HZSM-5分子筛进行La、P元素改性以及La-P复合改性，重点考察改性HZSM-5分子筛在溴甲烷甲基化苯制备对二甲苯反应中的催化性能，同时研究反应条件对该反应的影响。研究发现，对催化剂HZSM-5进行适当的改性能够提高对二甲苯的选择性和收率，12wt%La2O3、4wt%P2O5的La-P复合改性HZSM-5催化剂获得最佳的对二甲苯单程收率（13.4mol%）。对反应条件的研究发现，反应温度、溴甲烷与苯摩尔比和空速对对二甲苯单程收率的影响均出现极值现象，最佳的反应条件为：反应温度为450℃，溴甲烷与苯摩尔比为2:l，苯的WHSV为1.5h-1。 关键词：HZSM-5，苯，溴甲烷，对二甲苯，改性 The production of p-Xylene by methylation of benzene with bromomethane Abstract p-Xylene is an important basic raw materialthe petrochemical,and it is mainly used for production of terephthalie acidand dimethyl terephthalate，and then for production of polyester. Technological process of p-Xylene by shape-selective alkylation of toluene with methanol over HZSM-5 zeolite has been widely studied. However, it has been scarcely reported that p-Xylene is obtained by the methylation of benzene with bromomethane over HZSM-5 zeolite. In this dissertation, a series of HZSM-5 zeolite catalysts were modified by La, P and La-P , focusing on studying their catalytic performances in the methylation of benzene with bromomethane to produce p-Xylene. At the same time, the effect of the reaction conditions have been investigated. The study showed the catalytic performances of appropriate modified HZSM-5 were better than unmodified HZSM-5 in the selectivity and yield of p-Xylene. The best yield of p-Xylene (13.4mol%) was given over 12wt%La2O3-4wt%P2O5/HZSM-5. The experiments showed that the best reaction congditions were：reaction temperature was 450℃，the molar ratio of bromomethane to benzene was 2：l, WHSV was 6 h-1. Key Words: HZSM-5, benzene, bromomethane, modification 目 录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc295074474 第1章 绪 论 PAGEREF _Toc295074474 \h 1 HYPERLINK \l _Toc295074475 1.1对二甲苯工艺发展概况 PAGEREF _Toc295074475 \h 1 HYPERLINK \l _Toc295074476 1.1.