铬污染土壤电动修复中铬(VI)的解吸动力学研究-环境科学与工程专业论文.docxVIP

重庆大学 重庆大学硕士学位论文 英文摘要 PAGE PAGE VI ABSTRACT Heavy metal contamination of soil has given rise to a severe problem in China. The selection of remediation technologies is a key factor among the projects for tackling this problem. The cleanup technologies include the electrokinetic remediation (EKR), flushing, and phytoremediation. The removal efficiency of the EKR exceeds those of the flushing and phytoremediation when processing heavy metal contaminated clay. Two sequential steps control the removal rate of contaminants in EKR. The first step is the desorption of metal ions from soil particles, while the second is the electromigration of charged pollutants under the electric field, separating contaminants from the contaminated soil. Prevalent EKR theories hypothesize that the electric field exerts no effect on the ionic desorption, on which the EKR numerical modeling is based. One, however, cannot obtain any validation research of this hypothesis from global mainstream academic databases. Therefore, this dissertation studies the effect of the electric field on the metal ionic desorption for the purpose of verifying the aforementioned assumption through the comparisons with various desorption experiments (i.e. desorption kinetics experiments, electrokinetic desorption kinetics experiments, and column desorption kinetics experiments) via using the Cr-contaminated soil from a factory site. First, it performed desorption kinetics experiments, using two kinds of NaNO3 desorption solutions (0.05 and 0.5 mol/L). The comparison between two kinds of experiments turns out that NO3- is capable of competing the absorption site with the Cr (VI). The concentration of NO3- is proportional to that of desorbed Cr (VI). To eliminate the interference of various NO3- concentration, this research used 0.05 mol/L NaNO3 desorption solution in the subsequent experiments. Then, it shows that the amount of desorbed Cr (VI)of column desorption kinetics experiments is less than that of desorpt