等离子原位合成Fe基硼化物陶瓷熔覆层的研究-材料加工工程专业论文.docx

II II ABSTRACT Fe-Ti, Fe–B, B4C, Ti and Zr powders were used as raw materials and two powder systems of Fe-Ti+B4C, Ti+B4C, Ti+Fe-B and Zr+B4C, Zr+Fe-B were designed in this dissertation. Thus TiB2/Fe and ZrB2/Fe cladding coatings were respectively in situ synthesized on Q235 steel substrate by Plasma Transferred Arc (PTA) cladding. The optimal powder formulation and cladding procedures for preparing TiB2/Fe and ZrB2/Fe cladding coatings were determined after a large number of experiments. The phases and microstructures of the cladding specimens were analyzed by X-ray diffraction, optical microscope, scanning electron microscopy and energy dispersive spectrum. And the properties of the cladding coatings were carried out by microhardness, wear resistance and high temperature oxidation resistance tests. The results show that TiB2/Fe and ZrB2/Fe cladding coatings are successfully prepared with PTA powder cladding. Ti+B4C and Zr+B4C powder systems are fittest to precursor powders for the cladding coatings. It is better to control the dilution rates to about 65% for cladding coatings with good forming and excellent performances. From the top to the bottom of the cladding coatings, the contents of TiB2 and ZrB2 decrease gradually and the morphologies of reinforcement phases transit from coarse acicular to fine block shapes, which leading to gradual microhardness decreasing with gradient distribution. Main defects in Fe-based cladding coatings reinforced by in situ synthesized TiB2 and ZrB2 are incomplete fusion, surface imperfection, cracks, composition segregation, gas cavities and inclusions. Within Fe-Ti-B4C and Fe-Zr-B4C reaction systems, it was found by thermodynamic analysis that the metallurgical reaction between Me (Ti, Zr) and B4C is carried out with the highest driving force. Also, the reaction resultants of TiB2 and ZrB2 phases have the highest chemical stability. There are several paths for the forming modes of TiB2 and ZrB2 reinforcement phases inside the PTA