改性不饱和聚酯绝缘漆的耐热及导热行为-高分子化学与物理专业论文.docxVIP

华 华 中 科 技 大 学 硕 士 学 位 论 文 I I 摘 要 不饱和聚酯体系在耐热和导热性能方面的不足限制了它的进一步应用范围。为 获得性能优异的不饱和聚酯绝缘漆，本文采用不同的方法对不饱和聚酯绝缘漆进行 了改性。 首先采用环氧树脂对不饱和聚酯绝缘漆进行了改性，并研究了功能性溶剂苯乙 烯和乙烯基甲苯、交联剂二乙烯基苯（DVB）对不饱和聚酯绝缘漆性能的影响。结 果表明：用乙烯基甲苯作溶剂时，不饱和聚酯绝缘漆显示出更好的耐热性。添加少 量的DVB即可显著改善不饱和聚酯绝缘漆的耐热性能；绝缘漆的力学性能随着二乙 烯基苯（DVB）交联剂添加量的增加呈现先增加而后递减的现象；绝缘漆的导热性 能随着DVB含量的增加单调递增，而其介电损耗随DVB含量的变化表现出与导热性 能相反的规律。 其次，研究了乙烯基和氨基聚倍半硅氧烷（POSS）两种衍生物对不饱和聚酯树脂 力学性能、电学性能及耐热特性的影响。随POSS衍生物含量增加，不饱和聚酯绝缘漆 的粘接强度和电气强度均表现出先增加后递减的规律，而其介电常数呈现出先下降后 上升的趋势；添加POSS衍生物明显提高了不饱和聚酯绝缘漆的耐热和导热性能。 最后，依靠添加具有导热功能的氧化铝 (Al2O3)，氮化铝 (AIN)和二氧化硅 （SiO2）等填料，制备了不饱和聚酯导热绝缘漆。借助于热导率测试仪、高阻计、 TGA、FTIR、SEM 等分析手段研究了填料的种类、含量、分散工艺等因素对不饱 和聚酯绝缘漆的分散性能、热导性能、电绝缘性、热稳定性等的影响。结果表明： 采用磨砂机搅拌分散方式下填料在不饱和聚酯树脂中的分散及防沉降性最理想；添 加导热填料对不饱和聚酯的电学性能影响不大，但均改善了不饱和聚酯的导热性 能，其中，AlN/ Al2O3（纳米）混合填料对不饱和聚酯的导热性能提高最明显。 关键词: 不饱和聚酯绝缘漆；二乙烯基苯；不饱和基笼型倍半硅氧烷；填料 II II Abstract The shortcomings of unsaturated polyester in the heat-resistant and thermal conductive properties restrict its further application. In order to obtain unsaturated polyester with higher heat-resistance and themal conductivity, several methods were used to modify it in this dissertation. First of all, the epoxy was used to modify unsaturated polyester. And the effects of functional styrene and vinyl toluene solvents, divinyl benzene (DVB) cross-linking agent on the performance of insulating varnish were investigated. The experimental results showed that the unsaturated polyester possesses better heat-resistance when the vinyl toluene is used as solvent. A small amount of DVB can improve obviously the heat-resistance of the insulating varnish. The mechanical properties of insulating varnish increases firstly with increasing the DVB content. However, as the DVB content arrives at a particular amount, the mechanical properties become lower. The thermal conductivity of the insulating varnish has a trend of monotonic increasing with the DVB content, while its dielectric loss value exhibits the opposite variation regularity. Secondly, the effects of two types of polyh