粉末活性炭去除盐水中碘的研究-食品科学专业论文.docxVIP

重庆大学硕士学位 重庆大学硕士学位论文 英文摘要 PAGE PAGE VI ABSTRACT Iodine is essential trace elements to human, but excess intake of iodine will be harmful to the body. Some areas with high iodine concentration in water, it will need to reduce the iodine concentration can be edible. The iodine-removing technology has very big application prospect in food and other industry areas. Membrane cell technology is used in all new chlor-alkali plants. This is due to the fact that the expenditure concerning capital investment, operating costs and energy consumption, is lower than that of diaphragm and membrane technology. What is more, this is the most environmental friendly technology, yet this technology requires a high purity brine. One of the most important parameters to be monitored is the concentration of iodide ion. In the electrolysis cell, iodide is oxidized to iodate, which precipitates in the ion-exchange membrane and decreases the membrane’s useful lifetime. So the presence of iodide in brine is the direct reason leading to the damage of ion-exchange membrane. However, the ion-exchange membrane is quite expensive, the production costs will increase greatly if the ion-exchange membrane is changed frequently in chlor-alkali industry. Accordingly, removing iodide from brine is the most effective and economical method. In this study, the technique of H2O2 oxidation coupled with powdered activated carbon (PAC) to remove iodine from low concentration iodide-contained chlor-alkali brine was studied. The main contents include the following: ① In the process of oxidation of iodide, the optimum condition of iodide conversion was studied, some factors such as different oxidants, the molar ratio of hydrogen peroxide (H2O2) to I-, reaction temperature, pH value and the reaction time on iodide conversion were studied, and the results showed that: in the reaction of H2O2, the products are water and oxygen, which showed H2O2 is an suitable oxidant for iodide oxidation, comparing to ot