粉末活性炭应急处理原水农药类内分泌干扰物试验研究环境工程专业论文.docxVIP

哈尔滨工业大学硕士学位论文 哈尔滨工业大学硕士学位论文 哈尔滨工业大学硕士学位论文 哈尔滨工业大学硕士学位论文 PAGE PAGE IV III III Abstract In recent years, as agricultural development there are more and more dependence on pesticides. As a result, many kinds of pesticide Endocrine Disrupting Chemicals (EDCs) have been detected in source water for drinking water supply. These pesticides have stable chemical properties, with longer half- life period and hardly biodegradation. Especially in case of incidents of pesticides EDCs contamination, they may threat to human health due to the fact that it is not effective for conventional water treatment processes to remove them. In this paper, the adsorption technology using powdered activated carbon (PAC) was applied as an emergency treatment to remove pesticide EDCs from source water. Adsorption performances of PAC on four common pesticides (2,4-D、furadan、 atrazine 、 carbaryl) were studied by small-scale tests. The results showed that adsorption equilibrium of the PAC could be reached 60 min later, and about 90 % of removal efficiency could be achieved in deionized water. The study on adsorption kinetics of four pollutants showed that Lagergren second-order adsorption rate equation was much better than Lagergren second-order adsorption rate equation. The main process of adsorption of PAC was at the adsorption reaction stage. The results also showed that Freundlich isothermal adsorption had the best regression level, and the theory dosing rate of PAC could be calculated by using the above isothermal adsorption. In addition, the effects of PAC dosing rate, initial concentrations of contaminants and water quality on adsorption performance were investigated. By increasing the dosage of PAC, extending adsorption time, and reducing the amount of the background organisms, treatment efficiency could be improved even when source water polluted by high concentrations of EDCs. A pilot study on the removal of 2,4-D and furadan by PAC was carried out in moving emergency treatment guid