富氮工业生物质循环流化床解耦燃烧低NOx排放机理研究-化学工程与技术专业论文.docx

II II Abstract Distilled spirit lees, which is rich in cellulose, moisture as well as nitrogen, is a light industry biomass byproduct from the unique solid-state fermentation of distilled spirit in China. Distilled spirit lees has already considered as one of the important pollutions. Based on this background, IPE, CAS proposed and developed a circulating fluidized bed decoupling combustion technology(CFBDC), which was demonstrated to effectively treat spirit lees with large scale, clean and low NOx emission. However, the mechanism of low-NOx emission in CFBDC is not clear. Based on the CFBDC technology dividing combustion into the pyrolysis of distilled spirit Lees and reburning of distilled spirit lees pyrolysis products, we carried out this study from pyrolysis and reburning. A series of experiences were carried out in a laboratory fixed bed at the atmosphere of N2 for the purpose of better understanding the pyrolysis behavior of distilled spirit lees. The results showed that increasing the pyrolysis temperature from 500 ℃ to 850 ℃, caused the yield of char to decrease, to increase for pyrolysis gas and a parabola variation with increase first and then decrease for tar. At the temperature of 700 ℃, the yield of tar was highest. At the temperature of 500 ℃, there is no H2 detected in the pyrolysis gas. With the temperature increasing further, the content of H2 in the pyrolysis gas was increasing. At the temperature of 850 ℃, H2 was the main composition in the pyrolysis gas. For the compositions of CO and CO2, increasing the pyrolysis temperature caused their contents declining. A parabola variation with increase first and then decrease for CH4. At the temperature of 600 ℃, the content of CH4 was highest among the pyrolysis gas and reached 20%. GC-MS instrument is used to detect the tar compositions, which are produced in pyrolysis reaction, because of the complex compositions of tar. The compounds which is toluene, phenol, naphthalene and 1-h