稻壳预处理对稻壳灰的影响研究-动力工程及工程热物理专业论文.docx

哈尔滨工业大学工学硕士学位论文 哈尔滨工业大学工学硕士学位论文 万方数据 万方数据 Abstract Rice husk ash (RHA) is an agricultural waste material which has great industrial value. The main composition of RHA is silica. There are also some metal oxides and unburned carbon in RHA. High purity amorphous silica nano-particles can be obtained by combusting rice husk at low temperature which has good future of industrial application. However, with the increasing of combustion temperature, the black carbon residue content of RHA increases and the amorphous silica becomes into the quartz crystal, which could reduce RHA activity. Therefore, it was pointed out that high activity and purity RHA can be obtained by combusting rice husk which has been soaked in acid. Based on the above, the effects of different methods and combustion conditions on the properties of RHA were studied. The research methods were all follow, rice husk pretreated with 3kinds of acid (hydrochloric acid, sulfuric acid and acetic acid) in different concentrations (1%, 2.5%, 5% and 10%) for different time (0.5h, 1h and 2h), then the rice husk pretreated with acid combusted at different temperature (600, 700, 800 and 900℃) for different time (0.5h, 1h) in two combustion equipments (muffle furnace and fluidized bed). The microstructure and elemental composition of RHA were tested by XRF, SEM and EDS. Firstly, comparing RHA obtained from origin rice husk with that from acid pretreated rice husk, the reasons of high content of carbon residue and surface crystallization in RHA were analyzed. It was found that pretreatment could improve the performance of RHA, and increase the purity of silica. The effects of 3 kinds of acid pretreatment were discussed. It was found that hydrochloric acid pretreatment effect was the best. And then, the effect of pretreatment conditions and combustion conditions on the microstructure and elemental composition of RHA were also studied. There were critical conditions during pre-treat process which could affect the RHA cha