等离子体改性碳纳米管检测SF6放电分解组分的气敏特性分析-电气工程专业论文.docxVIP

重庆大学硕士学位 重庆大学硕士学位论文 英文摘要 PAGE PAGE VI ABSTRACT Due to high electric strength, excellent arc extinction performance, sulfur hexafluoride (SF6) is widely used in gas insulated switchgear (GIS). During long time operation, the internal insulation defects in GIS lead to partial discharge (PD). A part of SF6 is decomposed into different gas components under PD. The detection and analysis of these gas decomposition components is of great significance in condition assessment and fault diagnosis of GIS. There are some methods for the detection of SF6 decomposition components, but they have many deficiencies. Due to high sensitivity, low performance temperature and small size, gas sensor based on carbon nanotubes is fit for online monitoring of SF6 decomposition component. due to their structural limitations, intrinsic carbon nanotubes has good gas sensing response to only a few gases (NO2, NH3, etc.), so chemically modification is important for carbon nanotubes to improve its gas sensing properties. Chemically modified carbon nanotubes cross sensitivity to the presence of gas, and the sensitivity of the sensor and response recovery time has yet to be further improved. It is the selectivity of gas sensor to SF6 decomposition component need to solve. What’s more, the gas response sensitivity and response and recovery time need to be improved futher. In this paper, the plasma surface modification was used to modify the intrinsic carbon nanotubes. The dielectric barrier discharge plasma generating device was used to modify the carbon nanotubes wiht air plasma and CF4 which were two kind of typical plasma gas. The gas sensor based on the intrinsic carbon nanotubes and modified carbon nanotubes were prepared, respectively. These gas response characteristics of these gas sensors to H2S and SO2 which were two important SF6 decomposition characteristic components were studied by experiment, and the performance indicators of the gas sensors were measured, such as the resistance ch