氧化铁矿物催化分解苯酚的动力学速率及其产物特征.pdf

# # Bu lletin of M ineralogy , Pet rology and Geoch emis t ry V ol. 25 No . 4, Oct . 2006 吴大清, 刁桂仪, 袁 鹏 , 51064 0 本文研究了针铁矿纤铁矿赤铁矿和磁铁矿在过氧化氢参与下催化分解 酚的动力学速率与溶液p H 值的关系, 并 用紫外吸收谱测定了反应产物的谱学特征结果表明, 纤铁矿反应体系催化分解 酚的速率常数( k ) 最大, 其余依次为磁铁 矿针铁矿和赤铁矿在纤铁矿反应体系中又以pH = 3. 8 时反应速率常数最大除赤铁矿反应体系外, 当溶液p H = 3~ 4 时 酚被完全分解, 并有50% ~ 65% 的有机碳( T O C) 被矿化在pH = 3. 25 的赤铁矿反应体系中, 酚大多仅被转化为多酚, 小部分 环被打开形成己烯酸当溶液p H= 4 ~ 5 时, 酚 一般仅被转化为多酚类化合物, 但T O C 基本不变当溶液p H 5 时, 酚没有发生明显的转化和矿化现象 针铁矿; 纤铁矿; 赤铁矿; 磁铁矿; 催化分解; 酚; 动力学; 紫外吸收谱 O 62 1. 25 A 1007- 2 802( 2006) 04- 0293- 06 A Study on Kinetic Rates of Catalytic Decomposition of Phenol by Hydrogen Peroxide with Iron Oxides and the Characteristics of the Decomposing Products W U D a- qing, DIA O Gui- yi, Y U A N Peng Guangz hou I nstitute of Geochemistry , Chinese A cad emy of Sc iences , Guangz hou 5 10640, China Abstract T h e relation ship bet w een the kin etic rat es of catalyt ic ox idat ion of ph enol, b y H 2 O2 w ith goet hite, lepido- crocite, hematite an d m agn et it e in aqueou s solut ions at pH= 3- 6 under norm al room temperatu re, and th e pH val- u es of solution s has been investigat ed in this st udy. T h e spectrum charact eristics of th e decomposing product s w ere det erm ined by using ultraviolet spectrom etry . T he ex perim en tal res ult s in dicate t hat