铒掺杂对SrCaBi4xErxTi5O18压电陶瓷结构与电性能的.docVIP

铒掺杂对SrCaBi4.xErxTi5O18压电陶瓷结构与电性能的影响 目录 TOC \o 1-5 \h \z ? M I HYPERLINK \l bookmark4 \o Current Document \h Abstract II 弓I胃 1 HYPERLINK \l bookmark8 \o Current Document \h 压电材料概述 3 无铅压电陶瓷研究意义及现状 4 无铅压电陶瓷研究意义 4 铋层状压电陶瓷的特点 4 研究内容 5 1.3.1.研究内容 5 HYPERLINK \l bookmark13 \o Current Document \h SrCaBi4—xErxT i5018压电陶瓷的制备过程 6 2.1.药品试剂及仪器 6 2? 1 ? 2? ^3^ ?????????????????????????????????????????????????????????????????????????????????????????????????????????????? 7 HYPERLINK \l bookmark14 \o Current Document \h 实验工艺流程图 8 实验工艺过程 9 3.结果与讨论 3. 结果与讨论 10 X射线粉末衍射分析(XRD) 10 微观形貌分析(SEM) 13 陶瓷样品电性能测试 14 15 HYPERLINK \l bookmark27 \o Current Document \h 16 a w 17 钛酸铋钙SrCaBi4_xErxTi5O18（简称CBT）基无铅压电陶瓷是近年来研宄最广、最 具吸引力的钙钦矿结构的无铅压电陶瓷体系之一。但由于CBT具冇较高的矫顽场 和电导率，因而很难极化。因此，单纯的CBT陶瓷难以实用化。近年来，人们对 CBT基压电陶瓷进行了大量的改性研究。 本文将介绍通过固相烧结法制备SrCaBi4_xErxTi5O18,并利用D8 Advance X射线 衍射分析仪和JSM6380LV型扫描电镜分析、观测陶瓷样品的物象结构及表面微观 结构，利用介电、铁电测量方法对所制备的压电陶瓷的电学性能进行了初步的研 究。 研究结果表明，随着餌含量的增加，其品粒尺寸变小，介电常数也变小。由 介电温谱可知，该陶瓷体系的居里温度在32（TC左右，呈现弥散性相变的特征。 关键词:固相合成法；SrCaBi4-xErxTi5O,8；压电性能 关键词: Abstract Bismuth titanate calcium SrCaBi4 . xErxTi50is (CBT) lead-free piezoelectric ceramics is the most widely research in recent years, the most attractive one of lead-free piezoelectric ceramic perovskite structure system. But as a result of CBT has high coercive field and conductivity，so it is difficult to polarization. Therefore, simple CBT ceramics are difficult to practical application. In recent years，people of CBT based piezoelectric ceramics was studied by means of a lot of modification. This article describes preparation by solid phase sintering SrCaBi4 - xErxTi5O18, and use the D8 Advance X-ray diffraction analyzer and JSM6380LV type of scanning electron microscopy (sem) analysis，observation object structure and the surface microstructure of ceramic samples，using the dielectric, ferroelectric measurement method for the preparation of the electrical properties of piezoelectric ceramics has carried on the preliminary research.