KOH活化杨木制备活性炭特性研究.PDFVIP

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  • 2018-12-11 发布于湖北
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第 26 卷 第 4 期 天津科技大学学报 Vol.26 No. 4 2011 年 8 月 Journal of Tianjin University of Science Technology Aug. 2011 KOH 活化杨木制备活性炭的特性研究 李润霞,李占勇,董鹏飞,叶京生 (天津科技大学机械工程学院,天津 300222) 摘 要 :通过热重法对杨木颗粒以及用 KOH 浸渍后的杨木颗粒进行热解实验 ,通过 TG、DTG 、DSC 曲线的变化规 + 律 ,分析在主要失重阶段发生的物理变化、化学变化以及炭得率.结果表明 :活化剂 KOH 中的 K 对木材的热解具有 催化作用 ,形成活性炭的温度基本为 600, ℃,温度高于 800, ℃时,活性炭发生烧失反应;升温速率对炭得率几乎没有 影响 ;加入活化剂 KOH 后 ,提高了炭得率 ,但是炭得率与活化剂/杨木颗粒的质量比值成反比. 关键词 :杨木;化学活化;热重法;活性炭;炭得率 中图分类号:TQ351.21 文献标志码 :A 文章编号 :1672-6510 (2011)04-0044-04 Characteristic Study on Preparation of Activated Carbon from Poplar Wood by KOH Chemical Activation LI Run-xia ,LI Zhan-yong ,DONG Peng-fei ,YE Jing-sheng (College of Mechanical Engineering ,Tianjin University of Science Technology ,Tianjin 300222 ,China) Abstract :The pyrolysis experiments were carried out with the poplar wood and the poplar wood impregnated by KOH through the thermogravimetric analysis. The obtained TG/DTG/DSC curves were investigated ,and the chemical and physical changes in major degradation stages as well as activated carbon yield were analyzed. The results showed that the K+ in acti- vated agent KOH had catalytic effect on wood pyrolysis. Activated carbon was generally produced at 600,℃. T

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