合金化热镀锌镀层组织模拟及应用-材料科学与工程专业论文.docxVIP

湘潭大学 湘潭大学硕士学位论文 Abstract II II Abstract The demand for zinc-coated steel sheet has risen dynamically in recent years in the automotive industry, and the galvannealing coating (GA) has received most attention because of its excellent spot weldability along with superior corrosion resistance and better paintability. In the galvannealing process, the steel is first immersed in an alumi- num containing (approximately 0.135 wt.%) zinc bath and then given a post coating heat treatment. This heat treatment causes the zinc in the coating to inter-diffuse with the substrate iron to form several Zn-Fe intermetallics phases, including zeta (?), delta (?), gamma1 (?1), gamma (?). The problem of the flake off and the powdering during stamp- ing or forming of coated steel doesn’t be solved well. Therefore, it becomes important to understand the optimal microstructure and the better way of galvannealing process, which should be the primary study to solve the problem of the powdering. In the present work, a mathematical model for predicting the growth of zeta, delta, and gamma phases during the galvannealing process has been developed by using funda- mental diffusion data based on the primary diffusion species of zinc. The galvannealing may be characterized as a complicated finite/semi-infinite, multi-phase, volume diffusion problem. This implies that the diffusion of zinc in the three phases, ?, ?, and Γ, is to be considered along with the movement of the four interphase boundaries ?/?, ?/?, ?/Γ, Γ/?. The model has taken the incubation period of the Fe2Al5 layer breakdown, the amount of initial iron contributing to the coating during the breakdown of Fe2Al5 and the beginning time of formation of Γ into consideration. The problem can be solved numerically. A computer program was written in C language to obtain the simulation results. The values of iron content in the coating the thickness of Γ and the zinc concentration-distance profiles were predicted and compared to the data obta