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液相色谱-串联质谱法检测植物源食品中草甘膦及其代谢物的残留量
7 1 Vol. 7 No. 1
2016 1 Journal of Food Safety and Quality Jan. , 2016
成 婧, 王美玲, 龚 强, 徐瑞丽, 丁 利, 王利兵*
( , , ,
410004)
摘 要: 目的 -
方法 , , C18 , 9-
(FMOC-Cl), -结果
2
0.1 mg/kg 0.02 mg/kg, 5~100 ng/mL (r 0.999)
74.6%~96.5%, 0.041%~0.553%(n=6); 65.1%~79.4%,
0.024%~0.338%(n=6)结论 , , ,
,
关键词: ; ; ; ; -
Determination of glyphosate and aminomethylphosphonic acid residues in
plant-derived foodstuff by high performance liquid chromatography-tandem
mass spectrometry
*
CHENG Jing, WANG Mei-Ling, GONG Qiang, XU Rui-Li, DING Li, WANG Li-Bing
(Technology Center of Hunan Entry-Exit Inspection and Quarantine Bureau, State Key Laboratory of Food Safety Testing,
Hunan Key Laboratory of Food Safety Science Technology , Changsha 410004, China)
ABSTRACT: Objective To establish a method for the determination of glyphosate (PMG) and metabolite-
aminomethylphosphonic acid (AMPA) residues in plant-derived foodstuff by high performance liquid
chromatography-tandem mass spectrometry (HPLC-MS/MS). Methods After extracted with water under
ultrasonication, the samples were defatted with dichloromethane and then purified by C18 sol
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