火焰原子吸收光谱法测定甘蔗糖厂积垢中钙镁-甘蔗糖业.PDF

甘蔗糖业 2011 年第 2 期，2011 年 4 月 Sugarcane and Canesugar, No. 2, Apr. 2011 火焰原子吸收光谱法测定甘蔗糖厂积垢中钙镁 1,2 1 2 1,2 2 1 浦媛媛 ，陈 山 ，徐勇士 ，邹青松 ，陆海勤 ，莫海涛 1 2 ( 广西大学糖业工程技术研究中心，广西南宁 530004 ； 广西大学轻工与食品工程学院，广西南宁 530004) 摘 要：甘蔗糖厂积垢多存在于蒸发罐、糖浆过滤器及煮糖罐中，对生产过程和产品质量都有不利影 响。对糖厂蒸发罐、糖浆过滤器以及甲膏煮糖罐积垢进行湿法消解后，采用火焰原子吸收光谱法测定 各积垢样品中钙、镁含量，并对结果进行分析比较。运用该方法测得各积垢中钙含量为 206 ～266 mg/kg ， RSD 值为 0.21 ～2.28 ，加标回收率为 97.4% ～103.5%；镁含量为 0.4 ～2.22 mg/kg ，RSD 值为 1.31 ～3.34 ， 加标回收率为 95.2% ～106.4%，具有较好的准确度和精确度。 关键词：火焰原子吸收光谱法；甘蔗糖厂；积垢；钙；镁 中图分类号：TS247 文献标识码：A 文章编号：1005-9695(2011)02-0016-04 Determination of Ca and Mg Elements in Cane Sugar Factory’s Scale by Flame Atomic Absorption Spectrometry(FAAS) 1 1 2 1 2 1 PU Yuan-yuan , CHEN Shan , XU Yong-shi , ZOU Qing-song , LU Hai-qin , MO Hai-tao 1 2 ( Engineering Center for Sugarcane and Canesugar, Guangxi University, Guangxi Nanning 530004; Institute of Light Industry and Food Engineering, Guangxi University, Guangxi Nanning 530004) Abstract: Scales of cane sugar factory mainly exist in the evaporators, filters of syrup and vacuum pans, which are bad for the process and quality of production. Wet digestion method was used to scales from evaporators, filters of syrup and vacuum pans and contents of calcium and magnesium were determinated by flame atomic absorption spectrometry in digestion solutions of scales, the results were analyzed and compared. Using this method, the measured calcium content of scales was 206 ~ 266 mg/kg, RSD was 0.21~2.28, the recovery rate wa