淮河中下游水生态系统中PAHs的生物地球化学研究-环境科学专业论文.docxVIP

Abstract II more attention to and become a most important environmental monitoring object and treatment target from a source. The paper specially researched on the law of stable organic carbon isotopes of PAHs in sediment samples to discuss the origin of PAHs in the middle and low reaches of Huaihe River. It is the first time in the Huaihe River basin to apply this method to study sources analysis, and it can provide scientific basis for source control. Ten sampling sections were set up in the middle and low reaches of Huaihe River, and water samples, suspended substance samples and sediment samples were respectively collected in October 2008.Correspondently, the water samples and suspended substance samples were obtained through filtering, and the water samples extracted by liquid-liquid extraction (LLE). Accompanied with sediment samples, the suspended substance samples were extracted by soxhlet extraction (SE). And then all of the environmental samples cleaned up by sodium sulfate solution coupled with the columns of solid phase extraction, and finally determined by high performance liquid chromatography (HPLC) for content. Moreover, another sediment samples must be treated with hydrochloric acidwith the purpose of removing inorganic carbon before they were extracted by soxhlet extraction and enriched by silica gel column chromatography, and then the organic carbon stable isotopes were determined by gas chromatography combustion isotope ratio mass spectrometry (GC-C-IRMS).The research results showed as follows: The total PAHs concentrations in the water samples,suspended substance samples and sediment samples ranged within little difference, and the total PAHs concentrations in water samples from ZhengYangguan spot were the most, as well as that of suspended substance samples and sediment samples from BengBuZha spot. At the same time, the total PAHs concentrations of all the environment samples reflect the phenomenon that the sediment samples were the most among