淮南朱集井田煤中微量元素含量分布规律及其应用-环境科学专业论文.docxVIP

中国科学技术大学硕士学位论文 中国科学技术大学硕士学位论文 淮南朱集井田煤中微最元素含量分布规律及其应用 ABSTRACT By synthesizing amounts of the theories and advances about geochemistry of coal，this paper analyzed the characteristics of coal seams in Z：11uji Coal Mine， Huainan Coalfield employing theories related to geology, geochemistry, sedimentology and mathematical geology．In the pre-exploration stage，this paper explained the variation trends of moisture，volatile matter,ash yield and composition, calorific value，sulfur content and forms，organic and inorganic matters in 6 1 4 coal samples taken from 13 coal seams in 88 boreholes；in the additional exploration stage， this study ftLrther determined the contents of 47 elements in 520 coal samples，1 5 magmatic rocks，l parting and 1 roof by instruments of high precision such as ICP—MS and ICP-OES．The results show that-1)unvarying regularities are found from the vailation of moisture，volatile matter,ash yield calorific value，the abnormal values may relate with the locally geologic condition；coal—forming environments deduced from particular elements a呛consistent winl the evidence of paleo-sedimentary facies and fossils in boreholes，and which in turn are account for the coal quality parameters variation of different coal seams．2)By comparing the elemental abundances in China(North-China)，U．S．and world coals，the values for Zhuji coals are in normal range；the concentrations of some toxic elements such as As， Se，Sb，Pb and Cr are beyond the normal ranges，they will do harm to the ecological enviroments ifnot to be attention during exploited and utilization．3)Coal seam 3，4-I， 4—2 and 8 in some boreholes a托affacted by magmatic fluid,the elements in the coal ∞棚n will exchage with m剐姒resulting in elemental differentiation of these coal seams；the contrast of elemental contents between coal 9既lm affated by magmatic fluid and others will serves basis for evaluating magmatic erosion level and boundary． 4)Abundance variation of trace elements B(Sb)，Bi and Be(Zn)along 1 0 coal seams can