环保型三价铬镀铬工艺及铬层性质初探-冶金工程专业论文.docxVIP

F’’≯I{tl!顺一}：学似论文 摘要 摘要 (入价锵fU镀I：艺存祖：严巫的环境污染问题，干JJJtJ三价铬镀铬取1f|i代之 已经迎神涮睫。然而El前的三价铬镀铬工艺存在着镀液稳定性差、成本较 。临等缺点，使其成为电镀研究领域111的热点和难点之一d 木文探索了新型廉价铬源的制备方法，并应用赫尔槽试验，对三价铬 镀铬溶液的上要配方及成份进行研究。肋步明确了配方q一生盐和导电盐的 雌比、络合剂及涧濉剂种类及用量、特殊添JJIl剂种类及』仃量对镀层理化性 质的影n向方通过模拟生产试验，研究了三价铬工艺流程，探讨了电流密度、 *矗度、plI值、r【l镀时州等：L艺条1_l-x,J三价铬成膜性能的影响规律，并确 定了适合于1jip化牛产的_1：艺条件。 小义还从_E』k：l-产角度}Jj发，刈镀铬层理化特刊：提出了较为全而而实 川的评价指标体系，，}对三价铬镀铬层与标准六价铬镀铬层的各项性能指 标进行TXq比分析。／实验结果表明，本文采用的三价铬镀铬方法能电镀出 tl霆层光_}}J}、均匀、致密、抗蚀性好、硬度高的镀层，而I]．解决了镀层颜色 ㈨¨题，他i价锵锻层_i仪JL仃现j J：八价锵镀层的人|lfi：色光洋，㈨卜j还其 仃lIi流效率商、均镀能力与深镀能力好、工作lb流密度宽、设备简单、无 蚪境f‘染筲特J_。、} A刘镀{；}}层列11{二。陀能fiJ|=究办mi，沦文采川AFM首次观察到I乜镀1：艺 条件‘j镀层形貌、l钴粒尺寸、I镐粒生长规律之问的关系。jf：结合XRF、XRD 等驯究下．段，对不同。]j艺条件卜所得铍层的成份、结构、晶粒特征规律进 Ⅲ卅究，提jJj了三价铬镀铬的I乜镀机理，为深入研究三价铬镀铬=】：艺及工 、Jp化J、V川览定了艰础。 关键词： i价铬、Iu铍、原r力^＆微镜y[1ull槽试验 ，  -E戊I，j I sljl十学位论文 ABSqlRACT III AB STRACT Its urgent to develop the technique of trivalent chromium plating because of the heavy pollution of hexavalent chromium plating．The plating technique of trivalent chromium used now has many disadvantages such as low stability of solution，high cost of raw material．For the time being，there is still no perfect trivalent chromium plating technique having been used in industry in China．Thus the research on trivalent chromium plating attracts nlany concerns· Ill this paper，the preparation ofthe source ofchromium was explored． I lull cell test was used to have the research on the prescription of trivalent tin400liunl plating solution by single factor test and orthogonal test．The compositions and concentrations of main conductivity salt，comp|exing agent，wetting agent and special additive，as well as how they affect the quality and performance of deposited layer were determined．The technological process of trivalent chromium plating and the way of preparing the cheap chromium material were explored．The contribution of the technological parameter,such as current density，temperature，pH values and time to the trivalent chromiu