环保水乳型功能胶乳的制备表征及其应用研究-高分子化学与物理专业论文.docxVIP

2 2 扬州大学硕十学位论文 聚丙烯酸酯(PUA)复合胶乳，采用衰减全反射傅立叶红外光谱法(ATR．FTIR)、透射 电镜(TEM)、动态光散射(DLS)、热重(TGA)等技术对纳米复合胶乳的结构、尺寸 和性能进行表征。结果表明，复合胶乳的表面为PU中的亲水基团，内部为PU中的 疏水区域与PA形成的IPN结构，并揭示了复合胶乳的形成机理。与水性PU相比， 复合乳胶膜的耐水性及耐热性显著提高。应用于聚氯乙烯(PVC)片材的聚偏二氯乙 烯(PVDC)阻隔涂层的底涂剂，对比水性聚氨酯PVDC底涂剂，分析PVC片材表面 PVDC涂层表面外观、剥离强度、性价比等参数，指出PUA复合胶乳是一种性能优 异、价格低廉的新型水性PVDC底涂剂。 (3)采用两种功能单体甲基丙烯酸(MAA)和丙烯酰胺(AM)及乳液聚合方法成 功制备了高环氧树脂含量的环氧树脂接枝聚丙烯酸酯胶孚L(EPA)，采用DSC、萃取 法及铅笔硬度法对接枝共聚的乳胶膜进行结构与性能的表征。通过研究功能单体 种类与用量对乳液聚合稳定性及胶乳贮存稳定性的影响，揭示接枝聚合机理。系 统研究了EPA乳胶膜中环氧树脂的含量对交联度、玻璃化温度(劭、硬度以及交联 固化后的乳胶膜的耐水性能的影响。结果表明，MAA和AM两种功能单体共同使 用，使羧基(．COOH)、酰胺基(．CONH2)与环氧基团发生交联反应形成自交联结构， 是制备高环氧树脂含量的EPA的关键因素，EPA接枝共聚胶乳中环氧树脂含量从 10 wt．％～60 wt．％可调。共聚乳胶膜的自交联度、疋和硬度随着环氧含量的增加而 降低，而交联固化的胶乳膜耐水性能随坏氧树脂量的增加而提高。 关键字：乳液聚合，接枝共聚，功能胶乳，应用 戎潜萍：环保水乳型功能胶乳的制各表征及其应用研究 戎潜萍：环保水乳型功能胶乳的制各表征及其应用研究 3 Abstract The polyacrylate latex(PA)of molecular structure was designed changeably by varying the types and component of acrylic monomers．And thus the latex film from soft to hard、7l，ith distinct weather-resistant．water-resistant and chemical resistant．The PA latex has been widely used in interior and exterior wall coating，water-based adhesive， textile auxiliaries and other fields．In resent years，it is one of the more popular subjects of preparing polyacrylate complex latex with other properties of materials and other polymer materials to modify PA latex by chemical method to develop the novel application．Three kinds of complex latex system were studied in this paper,the first is inorganic nano—silica／polyacrylate hybrid complex latex，the second is polyurethane／ polyacrylate complex latex(PUA)，and the third is epoxy graft polyacrylate complex 1atex(EPA)． Nano silica exhibits attractive thermal，optical，electrical，magnetic and mechanical properties．Preparation of nano-Si02 in the PA latex expected to improve the heat resistance，comprehensive mechanical properties，UV and chemical resistance．However， due to the large surface and strong aggregation of nanosilica,the synthesis of stable nanosilica／polymer compl