环己基过氧化氢的分析方法研究-化学工程专业论文.docxVIP

研具有极大的应用价值，具有很大的发展前景。关键词 研具有极大的应用价值，具有很大的发展前景。 关键词 环已基过氧{宅氢分耩 瀵定 离子色谱 凝应高效液榴 色谱 AbstractCyclohexane Abstract Cyclohexane oxidation is the main process route on the production of cyclohexanone．The reaction of cyclohexane oxidation first produces cyclohexyl hydroperoide as all intermediate， and cyclohexanone can be attained via the dehydrogenation reaction。Since the chemical character of the cyclohexyl hydroperoide is not steady and can be decomposed easily,on the 50s一60s of last century,if the content of cyclohexyl hydroperoide is tOO high，it may bring chain decomposition reaction，just like the H202，the engineers was so worried that they enlarge the concentration of the catalyst，let the cyclohexyI hydroperoide in the aerobic environment(oxidation vessel)immediately and decomposed to cyclohexanone and cyclohexanol，in order to accelerate oxidation and ensure the safety．But the water which produced in high concentration catalyst cyclohexane oxidation reaction will dissolve the adipic acid，give birth to acidic sediment and block the pipe， affect the long period rurming of plant seriously and reduce the yield of cyclohexanone．On 80s of last century,DSM(Holland)developed the non—catalyst oxidation process，the cyclohexane oxidation reaction were controlled in cyclohexyt hydroperoide period primarily,and kept on low oxidation conversation ratio，so that attained higher oxidation yield。 The The quantitative analysis of the cyclohexyl hydroperoide which produced as an intermediate during the reaction have very important meaning in controlling the oxidation conversation ratio of cyclohexane oxidation reaction and increasing the yield of cyclohexanone，especially in how to control the alkali waste which produced during the decomposing of cyclohexyI hydroperoide and ensure the safety． The research of cyclohexyl hydroperoide analyse method are developed in recent and the relevant literature are seldom appeared。 This paper summarized the existing analyse method，anatomized