环己烷氧化废碱液中和利用的研究-环境工程专业论文.docxVIP

摘要 坼己烷氧化制备环己酮的无催化氧化与低温分解工艺，约有15-25％的环己烷 变成副产物。环己烷氧化废碱液是采用氢氧化钠溶液对环己烷氧化副产物进行皂 化处理而形成的废碱液，它是一种黑色粘稠液体，经测定，鹰化的环己烷氧化废 碱液COD值高达5．7×105m∥1，有机物总量达21 37％一29 66％，碱度在1400mmol／g 至1700mmol／g之间，密度稳定在1 24一l 29∥cm3之间。以往鹰化环己烷氧化废碱液 采用焚烧法处理，该法能有效地处理废碱液，但一年从中至少要跑掉7000多吨 有机物，其中有一部份是附加值较高的产品。通过查阅参考了大量的国内外文献，l。一 本文采用化学法对环己烷氧化废碱液综合利用进行了大量的研究工作：用硫酸中 和废碱液，分离后，水相进行萃取，萃取后的水相通过汽提、蒸发回收硫酸钠， 萃取后的油相经浓缩、结晶、汽提、脱色得己二酸：酸化分离的黑油经减压蒸馏、 精馏回收有机酸的工艺流程进行处理，而经化学法处理后废液的COD值大大降 低。本文通过大量的实验对环己烷氧化废碱液处理的各环节工艺条件进行了探 讨，回收了大量我国市场紧缺、附加值较高的产品，其综合利用比较全面，证明 了这一方案的可行性。 关键词：环己烷氧化 废碱液 中和 萃取 减压蒸馏  Abstract 111 the non．catalytic oxidation and low．temperature decomposition technology,there was about 15--25 percent by—products from the manufacture of cycloheoxane．Exhausted alkali lye produced in oxidizing process of cyclohexane was formed iIl血e saponification treatment,which was a kind of black viscous liquid and the value of COD was about 5-7×10气n鲋．Throughout determining．the organic content协exhausted lye reached 2 1．37％～29．66％and the alkalinity was about 1400 mulol／g～1700mm01／g，and the density was 1 24-1．29 g／cm3．h was used to burn this kind oflye for elminating the pollution． Facts showed it was effeclive．but as we know,there was at least 7000 tons of organic lost，and mnong them there was products owed fairly high extra value， In this paper,such research of comprehensive utilization of exhaused lye was canied on and a lots of documents were consuhed．We use sulphufic acid to neutralize waste lye．After separated and extracted sodium sulphate was recovered from water by steam stripping and evaporating，and adipic acid was acquired from oil by concentrating，crystallizing，steam stripping and decolorizing．The black oil produced ill acidulating and separating was treated by decompress distillation and rectification，Study showed that this kind of comprehensive utilization was fairly overall．Amounts of products which were short and owed higll extra value were recovered’and at the saule time，the value of COD iI】1ye reduced．