高光牢度数码印花活性墨水的制备及性能研究-应用化学专业论文.docxVIP

高光牢度数码印花活性墨水的制备及性能研究 Preparation and Properties of High Light Fastness Reactive Inks for Digital Jet Printing Abstract In this paper，to solve the problem of the poor light fastness of reactive dyes in reactive inks for digital jet printing，especially the poor light fastness of red dye，two methods were adopted．One way was to finish the cotton fabrics with the UV absorber containing reactive group．Another approach was to prepare high light fastness dyes．Meanwhile，reactive inks were prepared by these dyes， A虹nd of UV absorber was obtained from cyanuric chloride，m—aminobenzene sulfonic acid and 2一(2·hydroxy-5-sulfonicphenyl)一5一amino-benzotriazole．The yield of the product is 86．0％．Its purity iS 84．O％．and the solubility is I I 5 g／L at 25℃．The UV absorber was characterized by MS．IR and UV．Vis spectra．The molar absorptivity of the UV absorber iS 8365 L·m01-1．cm～at 336 nln．As it is hard to make sure that the digitaI iet printings were printed by one ink，pad dyeing cottons instead of the digital jet printings were used to study influnces of UV absorber on the light fastness of the dye．Reactive brilliant red K-2BP Was applied to cotton pad dyeing．The anti-UV finishing of the dyed cotton fabrics was carried with dip-pad·steam process．The relationship between concentration of the UV absorber and the fixation amount on cotton was investigated．The results showed that fixation amount increased with increase of concentration of the UV absorber．and the light fastness of the dye on cotton treated with the UV absorber increased by 0．5 grades． Yellow．red and blue reactive dyes containing 4-(5-hydroxy一3一methyl-1H-pyrazol·1一y1) benzenesulfonic acid were designed and prepared．The dyes were characterized by MS，IR and UV-Vis spectra．The yield ofthe yellow dye is 57，9％．Its purity is 87．3％．and the solubility is 1 60 g／L at 25℃．The maximum absorption wavelength of the yellow dye is 392 rim and the molar absorptivity iS 2．1×104 L-moll-cm一．The yield of the red dye is 58．7％．Its purity iS 89．2％．a