《煤及其衍生物的溶剂抽提》-毕业设计论文（学术).docVIP

┊ ┊ ┊ ┊ ┊ ┊ ┊ ┊ ┊ ┊ ┊ ┊ ┊ 装 ┊ ┊ ┊ ┊ ┊ 订 ┊ ┊ ┊ ┊ ┊ 线 ┊ ┊ ┊ ┊ ┊ ┊ ┊ ┊ ┊ ┊ ┊ ┊ ┊ 安徽工业大学 毕业设计（论文）说明书 共 45页 第 PAGE 1 页 煤及其衍生物的溶剂抽提 摘 要 本文通过对神府煤，准东煤及其不同前处理的煤样进行CS2-NMP混合溶剂抽提，并利用红外光谱、荧光、紫外、元素分析、GPC等分析技术对抽提物进行表征。 研究结果表明：神府煤中含有大量的脂肪结构，而准东煤中脂肪结构含量少。 CS2-NMP混合溶剂抽提物中主要是煤中富含脂肪族、醇和醚的组分，而抽提残煤中主要是富含缩合芳环的组分。神府煤的抽提率高于准东煤。 经氧解前处理的煤样，在氧解过程中产生大量的羰基，侧链氧化裂解，煤大分子芳香结构上产生羧基含氧官能团，所以有利于CS2-NMP混合溶剂的抽提。而经热溶前处理的煤样，在低于热解温度的热溶过程中，主要是煤结构热松弛引起的煤结构中非共价键缔合的分子化合物溶解，主要羰基化合物以及羟基与脂肪结构已在热溶过程脱除，所以该前处理过的煤样CS2-NMP混合溶剂的抽提率较低。 关键词：神府煤；准东煤；CS2-NMP抽提；氧化解聚；热溶 Solvent Extraction of Coal and its Residue Abstract In this paper, ShenFu coal, ZhunDong coal and its residues were extracted in CS2-N-Methyl-2-Pyrrolidinone mixed solvent (CS2-NMP), and the extractive was characterized by analysis technique of FTIR spectra, fluorescence, UV spectra, element analysis etc. The results indicate that ShenFu coal contains plenty of aliphatic structure, while ZhunDong coal contains little. It is also found that the solvent extractive contains abundent aliphatic, alcoholic and etheric components while the extraction residue contains abundent aromatic ring groups. In general, the extraction yield of ShenFu coal is higher than that of ZhunDong coal. As to the oxidation-pretreated coal, there generated plenty of carbonyl groups during oxidizing depolymerization, with sidechain alkyl of aromatic ring cracked, generating carboxyl oxygen-containing functional groups of macromolecule aromatic ring, so it is beneficial to extract in CS2-NMP. Whereas to the thermal extraction-pretreated coal, during the thermal extraction below pyrolysis temperature, the non-covalent bonds of associating molecules in coal were loosed, most of the carbonyl, hydroxyl and aliphatic groups were dissolved, which caused low extraction yield in CS2-NMP extraction. Key words: ShenFu coal; ZhunDong coal; CS2-NMP extraction; oxidizing depolymerization; thermal extraction 目 录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc327349292 摘 要