B位取代改性对BiFeO3BaTiO3基高温压电单相多铁陶瓷的结构压电及多铁性能的影响.docx

优秀毕业论文 精品参考文献资料 四川师范大学硕士学位论文oC 四川师范大学硕士学位论文 oC．1000 oC为三方和四方的两相共存；当温度升高到1030 oC时则完全变为四方。 当烧结温度从850 oC升高到1000 oC时，晶粒尺寸从1．02 gm增大到4．69“m。随 着烧结温度的提高，陶瓷的致密度、电绝缘性、铁电性、铁磁性和压电性均得到 了提高。在970 oC及以上的温度下烧结得到的陶瓷具有高的相对密度(94．7 ．95．9％)、良好的压电性能(如3=125—138 pCm)、强铁电性(尸r～13．2 i．tC／cm2) 和强铁磁陛(瞄=0．1 18 ernu／g)。 (3)采用的传统固相法制备O．75BiFel。Co；03．0．25BaTi03+l m01％Mn02多铁 性陶瓷，研究了Co掺杂和烧结温度对该体系的晶体结构、微结构、压电性以及多 铁性的影响。实验结果表明，Co掺杂使该体系的晶体结构从菱方变为四方，且增 强了该陶瓷体系的铁电性能和铁磁性。在X=0．10处，剩余极化只和剩余磁化 尬均达到最大值，分别为12,8 gC／cm2和0．97 emu／g。烧结温度的升高也使陶瓷晶 体结构发生了变化，在850．940 oC下烧结的陶瓷样品为菱方，当烧结温度升高到 970 oC和1000 oC时，陶瓷样品的晶体结构为菱方和四方共存相。在970．1000 oC 下烧结的X=0．02陶瓷样品具良好的铁电性能(B=14．5—21．6 gC／cm2)和铁磁性能 (坛=0．09-0．13 emu／g)。 关键词：BiFe03、单相多铁陶瓷、高温压电陶瓷、微结构、压电性、多铁性 II 万方数据 AbstractEffects Abstract Effects of B—site Substitution Oil S仃ucture， Piezoelectric and Multiferroic Properties of BiFe03--BaTi03--based High Temperature Piezoelectric／Single—phase Multiferroic Ceramics MajorMaterial Science Supervisor：Prof．Dunmin Lin Abstract Single-phase multiferroic materials possess the coexistence of magnetism and ferroelectricity in the sal／le material．BiFe03 is a rare single-phase multiferroic material and has been extensively investigated in recent years due to the coupling of ferroelectricity and ferromagnetism．It shows hJlgh Curie temperature Tc of 830 oC and N6el temperature Ts of 370 oC and thus may be a promising candidate for lead-free high temperature，piezoelectric and room-temperature multiferroic materials． In this thesis，the structure，mulfiferroic and piezoelectric properties of BiFel．xMx03一BaTi03(M：Al，Yb and Co)ceramics have been systematically investigated． The main results are listed aS follows： (1)0．725BiFel《舢x03—0．275BaTi03+lm01％Mn02 ceramics were prepared by a conventional ceramic technique．The effects of A1 doping and sintering temperature 011 micmstructure，piezoelectricity and magnetism of the ceral3缸CS were studied．The crystalline structures of BFO-BT-BA·X ceramics sintered at 970 oC for 2 h evolve from rhombohedral stru