fe3 in3 sb5共掺杂sno 2电极的制备与电催性能研究.docxVIP

优秀毕业论文 精品参考文献资料 AbstractWith Abstract With their broad application in the fields like coking，pesticide，wood manufacture，and petrochemical processing，more and more phenols and sulfur-containing organic compounds，are discharged in a form of industrial waste water．This has resulted in a serious pollution to water resources，because both phenols and sulfur．containing organic compounds are difficult to be degraded．In recent years， as to the treatment of phenols and sulfur—containing organic compounds，the technique of electrocatalytic oxidation，being more advantageous than others，has been attracting considerable attention all over the world．As electrode materials play a key role in electrochemical technique，this work would address the preparation and characterization of novel high．performanced electrodes and their application in the electrocatalytic oxidation of phenols and sulfur-containing organic compounds． Doped Ti／Sn02 DSA electrodes have been reported to possess many merits over others and to be used in the degradation of organic pollutant in waste water．In this work，three groups of doped Ti／Sn02 electrodes，Sn02：Sb5+，Sn02：SbS+-Fe3+and Sn02：SbS+．In3+，were prepared over Ti substrate via thermal decomposition method from precursor soIs COntaining chlorides of Sn+，Sb5+，Fe3+or In3+．Influencing factors， such as，the batch composition，the annealing temperatures，and the annealing time， were studied systematically,and the electrodes prepared were characterized by means of scanning electron microscopy(SEM)，energy dispersive X·ray spectroscopy(EDX)， cyclic voltammetry(CV)，and liner voltage sweep(LVS)．It is found that the electrocatalytic performance of Ti／Sn02 electrode was improved largely after doping． By optimizing preparation conditions，the doped Ti／Sn02 electrodes with composition of， Sn02：Sb5+(5％)，Sn02：Sb5+(5％)．Fe3+(O．5％)and Sn02：Sb5+(5％)一in3+(0．3％) prepared at an annealing temperature of 400 oC and an annealing time of 3 h，were identified to be the best perf