亚微米碳酸锰制备和形貌控制.PDFVIP

第35 卷第3 期 薛茹君等：硅烷偶联剂修饰改性的机理及改性绢云母的性能 · 377 · 第35 卷第3 期 硅 酸 盐 学 报 Vol. 35 ，No. 3 2 0 0 7 年 3 月 JOURNAL OF THE CHINESE CERAMIC SOCIETY March ，2007 亚微米碳酸锰的制备及形貌控制 吕春玲，张景林 ( 中北大学化工与环境学院，太原 030051) 摘 要：用硫酸锰和碳酸氢铵点接触反应法制备了亚微米级碳酸锰(MnCO ) ，分析了 MnCO 的粒度和形貌控制。用透射电镜和粒度分析仪表征了实 3 3 验结果。结果表明：由反应离子浓度决定的溶液过饱和度是影响MnCO3 粒度和形貌的关键因素，当离子浓度比[CO32–]/[Mn2+]在1～10 范围内增大时， MnCO3 粒度呈递减趋势；当[SO42–]/[Mn2+]在1～6 范围内增大时，MnCO3 的结晶速度减慢，而且晶型由不规则型向立方型过渡。另外，较高的超声频 率和较低的反应温度都有利于生成超细MnCO3 沉淀。实验中获得了400～500 nm 的立方型MnCO3 颗粒。 关键词：碳酸锰；粒度；形貌控制；离子浓度；超声频率；反应温度；点接触反应法 中图分类号：TB321 ；TB34 文献标识码：A 文章编号：0454–5648(2007)03–0377–04 PREPARATION AND SHAPE CONTROLLING OF SUBMICRON MANGANESE CARBONATE LÜ Chunling ，ZHANG Jinglin (Department of Environment and Safety Engineering, North University of China, Taiyuan 030051,China) Abstract: The drop-to-drop mixing method of manganese sulfate and ammonium acid carbonate was used to prepare manganese carbonate (MnCO ) particles. Particle size and shape controlling of MnCO was studied and discussed. Transmission electron micro- 3 3 scope and particle size analyzer were used to characterize the experimental results. The results indicate that supersaturation degree depending on ion concentration is very important for controlling the shape and size of MnCO3. The particle size decreases with the increased ratio of [CO 2–]/[SO 2–] from 1 to 10. Crystal speed of MnCO slows with the increased