防雾包装材料用助剂的研究-包装工程.PDF

摇 摇 摇 包 装 工 程 第35卷摇 第5期 摇摇摇 92 PACKAGING ENGINEERING摇 摇 摇 摇 摇 2014年03月 防雾包装材料用助剂的研究 1 2 万达 ,岳淑丽 (1.中山火炬职业技术学院,中山528436;2.华南农业大学,广州510642) 摘要: 目的摇 制备一种功能性核-壳结构复合微球。 方法摇 以过硫酸铵(APS)引发剂引发苯乙烯 (St)、丙烯酸(AA)和甲基丙烯酸甲酯(MMA)进行无皂乳液聚合。 采用红外光谱分析仪(FT-IR)对功 能微球的结构进行表征,通过扫描电子显微镜(SEM)和激光衍射粒度分析仪对产物的形貌、粒径大小 及分布进行分析,采用接触角测定仪(OCA)对材料薄膜与水的接触角进行测定。 讨论控制功能微球 形态、粒径及分布的影响因素,并研究功能微球薄膜在不同温度下亲水性的变化。 结果摇 功能微球为 亚微米级核-壳结构,该微球以PSt 为核,以亲水性的MMA-AA链段为壳,单分散性良好。 结论摇 在 25 益时功能微球涂覆薄膜与水的接触角为3毅具有最佳的超亲水性能。 关键词:无皂乳液聚合;防雾薄膜;微球;亲水性 中图分类号:TB485.9摇 摇 摇 文献标识码:A摇 摇 摇 文章编号:1001-3563(2014)05-0092-05 Additives in Antifogging Packaging Materials 1 2 WAN Da ,YUE Shu-li (1.Zhongshan Torch Polytechnic,Zhongshan528436 China;2. South China Agricultural University,Guangzhou510642 China) ABSTRACT:Objective To prepare a kind of core-shell functional microsphere. Methods Microsphereswere synthesized by soap-free emulsion polymerization methodwith styrene (St),methyl methacrylate (MMA) and acrylic acid (AA) using APS as initiator. Thestructureofthemicrospherewascharacterizedby FT-IR,themorphology andparticlesizeofthemicrospheres were evaluated by SEM and laser particle analyser. The water contact angel was measured by OCA. Factors influencing the morphology and particle size of the microsphereswerewell studied. Andthevariation of hydrophilicity of thefunctional micro鄄 spherefilm was studied at different temperatures. Results The as-prepared microspheres with PSt as core and MMA-AA as shell showed u