HACH 余氯原理说明书.pdfVIP

Current Technology of Chlorine Analysis for Water and Wastewater Technical Information Series — Booklet No.17 By Danial L. Harp Lit. no. 7019 L21.5 Printed in U.S.A. ©Hach Company, 2002. All rights are reserved. In memory of Clifford C. Hach (1919 – 1990) inventor, mentor, leader and, foremost, dedicated chemist Current Technology of Chlorine Analysis for Water and Wastewater Table of Contents Page 1. Overview of Chlorine Chemistry in Water Treatment 1 2. Analytical Methods for Chlorine and Chloramines 2 a. DPD Colorimetric Method 2 b. DPD Titration Method 5 c. Iodometric Titration Method6 d. Amperometric Titration Methods6 e. Other Analytical Methods: 8 Orthotolidine8 Syringaldazine (FACTS) 9 Electrode9 3. Method Interferences and Sources of Errors 11 a. Sampling Considerations 11 b. Interferences Common to All Chlorine Methods 11 Other Disinfectants11 Manganese Compounds12 Organic Chloramines 12 Bromides in Chlorinated Waters 12 c. Errors Common to Total Chlorine Determinations 12 d. Interferences in the DPD Methods13 Calibration Non-Linearity 13 Precautions in Using Permanganate as an Equivalent Standard 13 Monochloramine Interference in the Free Chlorine Test 15 Stability of the Colored Reaction Product 16 Compensation for Sample Color and Turbidity 16 e. Interferences in the Amperometric Titration Methods 17 Deposition on Electrode Surfaces 17 Manganese Interference17 Nitrite Interference