Zn掺杂SnS2SnO2复合材料的制备及其光催化性能.docVIP

Zn掺杂SnS2/SnO2复合材料的制备及其 光催化性能 殷立雄房佳萌柴思敏李慧敏白艺洋 陕西科技大学材料科学与工程学院 以五水合氯化锡(SnCl4 ? 51L0)和九水合硫化钠(Na2S.9H20)为原料，葡萄糖 酸锌(Zn (C6Hh07) 2)为添加剂，采用一步微波水热法制备Zn掺杂SnS2/SnO2复 合相纳米颗粒.采用XKD、TEM、光电流性能测试、拉曼强度对比等测试手段对所 合成的不同Zn掺杂量的材料结构和形貌以及性能进行表征，并以染料甲基橙 (M0)为0标降解物，研究了所制备的光催化剂在紫外光下降解有机污染物的性 能.结果表明，Zn摻杂之后复合材料的颗粒尺寸明显减小.Zn : Sn=l : 17摻杂材 料的拉曼光谱吸收峰的位置变化不大，较为稳定，并且该材料表而的载流子移 动速率最稳定.光催化降解甲基橙结果表明:Zn掺杂量为1 : 17时样品在20 min 之内，紫外光降解甲基橙效率可高达98%,表现出良好的光催化性能. 关键词： 掺杂;光催化;SnS2/Sn02;电子-空穴分离;颗粒尺寸; 殷立雄(W74-)，男，甘肃临洮人，副教授，博士，研宂方向：功能 薄膜及纳米材料 2017-10-18 基金：国家然科学基金项目 Photocatalytic property of Zn-doped SnS2/SnO2 nanoparticles prepared by a simple one-step microwave hydrothermal method YIN Li-xiong FANG Jiaieng CHAI Si-min LI Hui-min BAI Yi-yang School of Materials Science and Engineering， Shaanxi University of Science Technology; Abstract： Zn-dopcd SnS2/SnO2 nanoparticles were prepared by a simple one-step microwave hydrothermal method at a little Zn doping amounts, using SnCl4 ? 5H20 and Na2S ? 9 H20 as raw materials and Zn (C6HuO7) 2 as the additive agent. Structural, morphological of different doping amounts samples were characterized by using X-ray electron microscopy (TEM) ， Photocurrent responses, Roman spectra. The result confirms that the phase of SnS2 and Sn02 are successfully combined，and the size of the samples was decreased after dopped， obviously.The 1 : 17 sample possesses higher efficiency of charge separation and transfer. The range of variation Roman spectra is low when the molar ratio (Zn : Sn) reached to 1 : 17. Furthermore, the photocatalytic properties of the nanocomposites were tested for the degradation of methyl orange (MO) in water under ultraviolet light, greater than 98% photodegradation of MO was achieved within 20 min with the composites prepared while the molar ratio (Zn : Sn) reached to 1 ?? 17, which displayed remarkably promoted photocatalytic activities. The Zn doping amounts to composite nanoparticles was considered to play an significant role in attaining the high