不同化学结构电子中介体以作为微生物媒介传递-中国鑛冶工程学会.PDF

不同化學結構電子中介體以作為微生物媒 介傳遞電子及還原脫色之比較研究 Comparat ive St udy of Microbially -Mediat ing Characterist ics of Electron Transport and Reductive Decolorization Using Electron Shuttles with Diverse Chemical Structures 1 2 3 S.C. Liu, P.L. Yueh, P.Y. Chen Prior studies (Chen et al., 2012) disclosed that some decolorized intermediates (e.g. 2-aminophenol) could act as mediator(s) to enhance the capability of reductive (Benzene-1,2- decolorization and bioelectricity generation. This study diol) (1,2-Diaminobenzene) selected model compounds with auxochromes (e.g., benezene- 1, 2-diol, 1,2-diaminobenzene) to explore how chemical structure(s) affected color removal and power producing capabilities in microbial fuel cells (MFCs). The cyclic voltammetry, respiratory testing and MFC data showed electron-shuttling capabilities Proteus hauseri (ZMd44) of aforementioned compounds using Proteus hauseri Acinetobacterj ohnsonii (NIUx72) ZMd44, Acinetobacter johnsonii NIUx72 seeded MFCs. Results of this study indicated that chemical structure(s) of decolorized mediators directly affected characteristics o f s i m u l t an e ou s r e du c t i v e d e c o l or i z at i on an d bioelectricity generation in MFCs, suggesting feasible operation strategy of MFCs for industrial applications. 關鍵字： Key words: Micr ob ial fu el cell ; Electr on shuttle ; Auxochrome; Reductive decolorization 一、前　言 (Campbell et al., 2006) 2011