硅粉在混凝土中的应用.pptVIP

* Second step in the pozzolanic reaction. The CSH gel formed in this reaction is essentially identical to that formed in the initial reaction of portland cement and water. * This figure shows the reduction in calcium hydroxide content of a mature cement-silica fume paste with a water-cement ratio of 0.60. This information is further evidence of the pozzolanic nature of silica fume. From: Sellevold, E. J., Bager, D. H., and Klitgaard Jensen, E., “Silica-Fume Cement Pates: Hydration and Pore Structure,” Condensed Silica Fume in Concrete, Report BML 82.610, Norwegian Institute of Technology, Trondheim, 1983, pp. 19-50. conc701.1 * P. K. Mehta describes the transition zone in his textbook, Concrete: Structure, Properties, and Materials. ACI Committee 234 describes the role of silica fume in the transition zone in the committee document, ACI 234R-96, Guide to the Use of Silica Fume in Concrete. * Schematic of the transition zone. Note that in the area adjacent to the surface of an aggregate particle, the relatively uniformly sized cement grains are not packed as densely as they are in the bulk zone. This “wall effect” is one of the reasons stated for the relative weakness and permeability of cement paste in the transition zone. When silica fume is added to the concrete, better particle packing occurs in this area. The silica fume in this area can further refine the transition zone through its pozzolanic reaction. This sketch is taken from H. H. Bache, “Densified Cement/Ultra-Fine Particle-Based Materials,” Presented at the Second International Conference on Superplasticizers in Concrete, 1981. conc698.2 * Socket where a sand grain has been pulled away from cement paste in 1-day old mortar. The sand grain was originally at the top of the picture. Note the open structure and the presence of crystals of calcium hydroxide in this region. “In portland cement mortars, the microstructure of the interfacial zone, extending to about 20 to 50 μm from the sand gra