Mn-TiO2系列催化剂氧化还原性能以及其在低温SCR下对NOx去除效果的影响.docxVIP

PAGE \* MERGEFORMAT PAGE \* MERGEFORMAT 1 PAGE \* MERGEFORMAT PAGE \* MERGEFORMAT １ Mn/TiO2系列催化剂氧化还原性能以及其在低温SCR下对NOx去除效果的影响 摘 要：由于低温SCR催化剂的抗硫性能不足,本文研究了通过加入新元素提高了催化剂的氧化-还原能力对SCR反应的活性以及催化剂的抗硫性。试验中我们采用用溶胶-凝胶法添加Zr元素制备新型催化剂并测试它对SCR反应的催化效率及抗硫性。选择催化效率高的催化剂进行各种物理化学方面的表征，探究催化剂的氧化-还原性对于低温SCR的影响。发现添加Zr不仅可以提高催化剂的活性，还可以提高催化剂的抗硫性，并且找到了Zr添加的最佳比率。最终通过表征的结果探明催化剂氧化还原性对低温SCR反应影响的机理。 关键词：Mn/TiO2催化剂；氧化还原性能；添加Zr；NO2形成；L-H机理 The redox ability of the Mn/TiO2 catalysts and its effect on NOx removal in low-temperature SCR Abstract: Due to the resistance to SO2 of SCR catalyst for low temperature SCR, we want to improve the redox ability and the sulfur tolerance of the catalyst by adding Zr. The catalyst was prepared by sol-gel method. The catalyst with high catalytic efficiency and explored the effect of oxidation-reduction ability of catalyst on low-temperature SCR reaction by several of physical and chemical characterization. We found that adding Zr can not only improve the activity of the catalyst, but also improve the sulfur resistance of catalyst. We found the best ratio of Zr addition, and got the mechanism of the effect of oxidation-reduction ability of catalyst on low-temperature SCR reaction. Keywords: Mn/TiO2 catalysts; Redox properties; Adding Zr;NO2 formation; Mechanism of L-H 正文目录 TOC \o 1-2 \h \u HYPERLINK \l _Toc24705 1引言 I-4 HYPERLINK \l _Toc29204 1.1 研究背景 I-4 HYPERLINK \l _Toc617 1.2 研究意义 I-5 HYPERLINK \l _Toc27326 2材料和方法 I-6 HYPERLINK \l _Toc3421 2.1 实验材料 I-6 HYPERLINK \l _Toc5327 2.2 催化剂制备 I-6 HYPERLINK \l _Toc56 2.3 催化剂的活性测试 I-6 HYPERLINK \l _Toc2478 2.4 表征分析方法 I-6 HYPERLINK \l _Toc22376 3结果与讨论 I-8 HYPERLINK \l _Toc16436 3.1程序升温还原研究 I-8 HYPERLINK \l _Toc23712 3.2程序升温脱附研究 I-9 3.3 DRIFT研究 I-10 4结论与建议 I-17 HYPERLINK \l _Toc24256 4.1结论 I-17 HYPERLINK \l _Toc5395 致谢 I-18 HYPERLINK \l _Toc13002 参考文献 I-19 1引言 1.1研究背景 随着社会经济的快速发展，钢铁冶炼、火力发电、