印染废水CWAO法处理中均相催化剂的研制-JournalofNortheastern.PDF

第30 卷第8期 东 北 大 学 学 报 ( 自 然 科 学 版 ) Vol30, No. 8 2 00 9 年 8 月 Journal of Northeastern U ni ersity( Natural Science) Aug. 2 0 0 9 CWAO 张永利, 李 亮, 胡筱敏 ( , 110004) : , COD 2 000 mgL- 1 , , COD 19 , : , Cu1Fe1 , COD 50% Cu 1Fe1 , Fe( ) : ; ; ; ; : X703. 1 : A : 1005-3026( 2009) 08- 1189-04 Preparation of Homogeneous CWAO Catalysts to Treat Dyeing- Printing Wastewater ZH A N G Yong-li, LI L iang, H U X iao-min ( School of Resources Ci il Engineering , Northeastern Uni ersity, Shenyang 110004, China. Correspondent: HU Xiao-min, professor, E-mail: hxmin jj @ 163. com) - Abstract: To prepare the CWAO catalysts to treat high-concentration dyeing-printing w astew ater, an experiment w as done to degrade the methylene blue aqueous solution as sample, - 1 of w hich the COD alue is up to 2 000 mg L , w ith homogeneous CWAO process. The performance of those catalysts was e aluated w ith COD remo al rates and decoloring rates. Among the 19 kinds of soluble salts, some double-component catalysts were chosen and resynthesized. The results show ed that the leading catalytic acti ity is of copper/ iron salt, while the Cu1Fe1 catalyst resynthesized by copper sulphate and ferrisulphas is superior in both acti ity and cost and its COD remo al rate in the sample wastewater increases by about 50% in comparison to that w ithout the catalyst used. The mechanism analysis of Cu1Fe1 catalyst show s that the free-radicle reaction and coagulation of Fe ( ) polymer both function simultaneously. Key words: w astew ater treatment; CWAO ( catalytic w et air ox idation ) ; catalyst; dyeing