分级冷凝生物油组分富集与组分稳定性研究.PDF

第46卷 第11期 燃摇 料摇 化摇 学摇 学摇 报 Vol.46 No.11 2018年11月 Journal of Fuel Chemistry and Technology Nov. 2018 分级冷凝生物油组分富集与组分稳定性研究 王摇 储,朱锡锋* (中国科学技术大学 工程科学学院,安徽 合肥摇 230026) 摘摇 要:利用GC鄄MS分别检测分级冷凝装置和常规冷凝装置制备的核桃壳生物油,对比常规冷凝生物油与分级冷凝多品级 生物油有机组分的相对峰面积,发现分级冷凝对组分富集有较大影响,其中,乙酸在第四级生物油内相对峰面积从5.38%上 升至9.44%;愈创木酚在第二级内从3.46%上升至6.23%;紫丁香醇在第一级内从1.48%上升至4.44%;异丁香酚在第一级 内从5.52%上升至17.84%。 经过75d、15益恒温恒湿储存后分级冷凝生物油水分增加,分别增加了1.58%、1.88%、1.80%、 2.43%;脂肪类有机物峰面积减小;酚类有机物峰面积增大。 第一、二级生物油内小分子有机物含量较少,老化反应强度较低; 第三、四级生物油内小分子有机物含量较多,老化反应强度较高。 根据GC鄄MS检测结果将有机物分类,统计各类有机物在储 存前后的含量变化,分析储存过程中各类有机物发生的老化反应种类以及反应强度。 关键词:生物油;分级冷凝;组分富集;组分分析;储存稳定性 中图分类号:TK6摇 摇 摇 摇 文献标识码:A Study on component enrichment and storage stability of bio鄄oils obtained from fractional condensation WANG Chu,ZHU Xi鄄feng* (School of Engineering Science,University of Science and Technology of China,Hefei摇 230026,China) Abstract:Thebio鄄oilsfrom ordinary condensation andfrom fractional condensation wereanalyzedby GC鄄MS. Comparing therelativepeakareasofthese,theresult showsthatthefractionalcondensationhasan obviouseffect on component enrichment. The acetic acid in the 4th step condensation increases from 5.38% to 9.44%,the guaiacol inthe2nd step condensationincreasesfrom3.46% to6.23%,andthe sringolandisoeugenolinthe 1st step condensation increase from 1.48% to 4.44% and from 5.52% to 17.84%,respectively. After 75 days storage stability experiment on the physicochemical properties of multi鄄fraction bio鄄oils obtained from fractional condensation in a 15 益 constant temperature and humidity box, the water content of the fractional bio鄄oils increasesby 1.58%,1.88%,1.80% and 2.43%,respectively. Besides,the acids,aldehydes,ketones and alcohols decrease after sto