小晶粒ZSM-5沸石的绿色经济性合成-物理化学学报.PDFVIP

物 理 化 学 学 报 920  Acta Phys. -Chim. Sin. 2018, 34 (8), 920–926    [Article] doi: 10.3866/PKU.WHXB201801111 Green and Cost-Effective Preparation of Small-Sized ZSM-5 XUE Teng 1, DONG Lilu 1, ZHANG Ying 1,2, WU Haihong 1,* 1 Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200062, P. R. China. 2 Shanghai University of Medicine Health Sciences, Shanghai 200237, P. R. China. Abstract: Small-sized zeolite ZSM-5 for a wide SiO /Al O ratio 2 2 3 range was prepared using a small amount of colloidal silicalite-1 as the active seeds. The thus-prepared small-sized ZSM-5 samples have been characterized using X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), N2 adsorption-desorption analysis, temperature-programmed ammonium desorption (NH3-TPD) analysis, and adsorbed pyridine infrared spectroscopy (Py-IR). The use of the active silicalite-1 seeds was effective in directing the reaction towards the formation of the MFI phase, avoiding the impure phases and reducing the crystal sizes. The prepared sample exhibited aggregated morphologies when a lower ratio of starting batch SiO /Al O (SiO /Al O ratio = 30) was used. The aggregates, with the size of ~500 nm, were formed with 2 2 3 2 2 3 2 −1 nano-sized primary crystals 50 nm in size, possessing large external sur