用重结晶法和氟化沉淀法实现镁锰分离.DOCVIP

doi：10.3969/j.issn.1007-7545.2012.08 doi：10.3969/j.issn.1007-7545.2012.08.013 杨超，王文磊，曾德文，阳海棠，陈聪，陈启元 （中南大学 化学化工学院，长沙 410083） 摘要：分别采用重结晶法和氟化沉淀法脱除硫酸锰溶液中的杂质镁。用Pitzer热力学模型对二元系MgSO4-H2O、MnSO4-H2O和三元系MgSO4-MnSO4-H2O的溶解度相图进行模拟预测，并结合溶解度相图对三元系的固溶体用重结晶法验证其分配比。同时采用氟化沉淀法进行对比试验。结果表明，由于固定分配比，重结晶法对镁锰分离作用十分有限，而加入MgF2晶种的氟化沉淀除镁新方法能够有效提高氟化沉淀法的效率，在95 ℃下，加入0.3 g氟化镁晶种和250%理论用量的NH4F搅拌1 h，能使镁的除去率达到94.3%。 关键词：Pitzer模型；相图；分配比；重结晶；氟化；晶种；MnSO4溶液；镁 中图分类号：TF111.34 文献标识码：A 文章编号：1007-7545（2012）08-0000-00 Study on Magnesium Removal in Manganese Sulfate Solution YANG Chao, WANG Wen-lei, ZENG De-wen, YANG Hai-tang, CHEN Cong, CHEN Qi-yuan (School of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China) Abstract: Magnesium impurity was removed by recrystallization and fluoride precipitation in manganese sulfate solution, respectively. The solubility isotherms of binary systems MgSO4-H2O, MnSO4-H2O and ternary system MgSO4-MnSO4-H2O were simulated and predicted with Pitzer thermodynamic model, and the distribution ratio of MgSO4 and MnSO4 in solid phase-liquid phase was verified via HYPERLINK dict://key.0895DFE8DB67F9409DB285590D870EDD/recrystallization \o 查找: recrystallization recrystallization experiment. Mg was also removed by fluoride precipitation compared with the former. The results show that HYPERLINK dict://key.0895DFE8DB67F9409DB285590D870EDD/recrystallization \o 查找: recrystallization recrystallization exerts quite limited effect on the separation of Mg and Mn due to constant distribution ratio, and the efficiency is improved by adding MgF2 crystal seed in fluorination. The removal rate of Mg is 94.3% at 95 ℃ with 0.3 g MgF2 and 250% NH4F for 1 h. Key words: Pitzer model; solubility isotherm; distribution ratio; HYPERLINK dict://key.0895DFE8DB67F9409DB285590D870EDD/recrystallization \o 查找: recrystallization recrystallization; fluorination; crystal seed; MnSO4 solution; magnesium 随着锰系电化产品的升级换代，用户不仅要求产品的纯净度高，而且要求物理性能好、电化学性能稳定。要达到上述要求，就必须控制进入电解液的杂质含量。锰浸出液中杂质离子