超疏水涂膜的研究进展3.PDF

第 18 卷 第 11 期 化　学　进　展 Vol. 18 No. 11 2006 年 11 月 PROGRESS IN CHEMISTRY 　Nov. , 2006 超疏水涂膜的研究进展 曲爱兰　文秀芳　皮丕辉　程　江　杨卓如 (华南理工大学化工与能源学院 　广州 510640) 摘 　要 　超疏水涂膜以其独特的性能 ,在国防、工农业生产和日常生活中有着广泛的应用前景。但目前 的制备技术制约了其在建筑外墙涂料等大型设施方面的应用。探索如何采用简单有效的方法构造和调控涂 膜的双微观结构 ,从而获得性能持久优异的超疏水性涂膜 ,并有效应用于生产和生活的各个方面是这一领域 研究的最终目标。本文就超疏水材料表面理论的发展和近几年来超疏水膜制备技术取得的新成果进行了概 括 ,并指出制备超疏水涂膜存在的问题和发展方向。利用表面能极低的含氟材料 , 将溶胶凝胶、相分离技 术和自组装梯度功能等技术有机结合 ,获得适宜的表面粗糙度和微观构造 ,是实现超疏水涂膜工业化生产的 可行途径。 关键词 　超疏水膜 　接触角 　表面双微观结构 　梯度功能 ( ) 中图分类号:O647 ; TB43 　文献标识码 : A 　文章编号 : 1005281X 2006 Studies on SuperHydrophobic Films Qu Ailan 　Wen Xiufang 　Pi Pihui 　Cheng Jiang 　Yang Zhuoru ( The School of Chemical and Energy Engineering , South China University of Technology , Guangzhou 510640 , China) Abstract 　Superhydrophobic film is of promise prospect applied in various industrial products. But it is limited by preparing techniques for use as coatings of outside building and large equipments. It is the aim to search simple and effective methods to prepare and control the micronanobinarystructure to get superhydrophobic coating. Here we briefly review the development of the theory and recent progress in the process and properties of superhydrophobic films. It is a possible way to realize industrial production of superhydrophobic coating with appropriate roughness and microstructure by the combination of different technologies such as solgel , phase separation and selfassembly of low surfaceenergy materials. Key words 　superhydrophobic film ; contact angle ; micronanobinarystructure ; gradient func