紫外激发白光LED用三基色荧光粉的制备与性能分析.pdfVIP

摘 要 粉是一种发光性能比较好的蓝白色荧光粉。 利用 Sm3+离子作为激活剂采用高温固相法制备了 Ca SiO Cl :xSm3+红色荧光材料。 3 4 2 测量了荧光粉的 XRD 衍射谱，激发光谱和发射光谱。在紫外光的激发下，该荧光粉的 发射光谱为峰值位于 564nm、608nm 和 648nm 的三峰谱线，其中位于 648nm 处的红光 发射最强。监测 648 nm 发射峰得到的材料的激发光谱主峰位于 363nm、376nm 和 404nm 的线状谱线，说明该荧光粉可被紫外光和近紫外光有效的激发。研究了 Sm3+ 的掺杂浓 度对样品发光性能的影响及猝灭机理。结果表明该荧光粉是一种较好的用于白光 LED 的红色发光材料。 关键词 白光LED 激发光谱 发射光谱 浓度猝灭 能量传递 II Abstract Abstract White light-emitting diodes (LEDs) are considered to be the next generation solid state lighting devices due to their attractive attributes such as durability, small volume, long lifetime and environment friendly. The development of LEDs is accelerated with the arising of effectively near UV chip that can emit 350~400 nm light, which put forward higher requirements for effectively tri-color phosphor that can be excited by near UV light. A novel Sr SiO :Eu2+ phosphor was synthesized by high temperature solid state method. 3 5 The emission spectra are composed of two emission bands centered at 476 and 578 nm, respectively when the concentration of Eu2+ ions is lower. The blue emission peak weakens gradually with increasing of Eu2+ concentration and disappears when Eu2+ concentration reaches 1 mol%. The yellow emission peak enhances with Eu2+ concentration and the concentration quenching occurs when Eu2+ concentration reaches 1 mol%. The critical distance Rc are 3.06 and 2.62 nm, respectively according to Dexter theory and Blasse equation. Furthermore, Eu2+ ions have energy t