双功能催化剂应用于多步催化反应中的研究-有机化学专业论文.docxVIP

Abstract Abstract 上海师范大学硕士学位论文 showedgreat catalytic activity with high conVersion(con： 99％)and enantioselectivity (ee：97％)，and the chiral transition Es value was from 95％t01 00％．Throughout the reaction，the catalyst utilizd the affinity of substrate and material to improve the efficiency of the reaction，and after that it could be recycled eight times with efficient catalytic activity．All in all，we thought it had a broad application prospects． (2)With the polyoxypropylene．polyoxyethylene copolymer being the template， the functional chiral silica source(足尺)4-(trimethoxysilyl)ethyl)phenylsulfonyl·1,2一 diphenylethylene-diamine and tetraethoxysilane(TEOS)were used to synthesize support material of the catalyst by hydrolysis under acidic conditions．Then we supported chiral mesitylene ruthenium catalyst by coordinating and immobilized a gold catalyst by the process of hydrogen adsorption to form the Au-Ru bifunctional catalyst．Finally we successfully apply it to the One-Pot hydration-asymmetric transfer hydrogenation reaction to get a series of chiral halogenated aromatic alcoh01． After testing the catalytic activity，we found that the catalysts showed great catalytic activity with high conversion(con：92％)and enantioselectivity(ee：99％)．Throughout the reaction，the catalyst showed high catalytic activity，and after that it could be recycled eight times with efficient catalytic activity．All in all，we thought it achieved the goal of green chemistry． Keywords：Periodic Mesoporous OrganosilicasMaterial；Supported Catalyst； Asymmetric transfer hydrogenation；Isomerization；Cascade reactions． IV 万方数据 上海师范大学硕士学位论文 上海师范大学硕士学位论文 目录 目 录 摘要 ．．I Abstract ． ．．I】[I 第一章：研究背景 l 1．1绿色不对称催化 l 1．1．1手性化合物 一1 1．1．2绿色化学中的不对称有机催化 ．．2 1．2介孔硅纳米材料 ．3 1．2．1介孔硅纳米材料的功能化 ．．4 1．2．2无机介孔硅材料及其应用 ．6 1．2．3有机介孔硅材料及其应用 一8 1．3多金属催化的串连反应 10 1．3．1多催化剂催化反应的概述 10 1．3