基于聚多巴胺的表面增强拉曼基底的制备及应用-分析化学专业论文.docxVIP

优秀毕业论文 精品参考文献资料 ．．A ．．A．．．．．．．b．．．．s．．．．t．．r．．．a．．．．c．．．．t．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．．—— Shanghai Normal University Master of Dissertation． 84．1％一I 12．5％．Also，the proposed easy assay of PDA@AgNPs combining with portable Raman system is simple，economic and high sensitivity． Melamine，due to its high nitrogen content，are often mixed into milk，can caused high protein phenomenon，and long-term consumption harm to the body． Therefore，it is necessary to explore accurate，easy and reliable analytical protocol to determine the content of melamine in milk．We then use polydopamine as protective agent to prepare core-shell Au@Ag@PDA nanoparticles．After series of characterization，Au@Ag@PDA conducted the SERS substrate detecting melamine in milk．The limit of detection(LOD)of melamine in water is 0．3 gg／L， with an excellent linear range of 0．5-20}．tg／L，and the recovery of melamine in milk is 89．4％一109．5％． The research shows that the SERS substmtes based polydopamine，have good reproducibility and sensitivity，and can realize the detect acrylamide in drinking water and melamine in milk．There is doubt that the rapid，sensitive detection technology，Raman spectroscopy be applied in the testing of and environmental monitoring and food safety． Key words：SERS；polydopamine；silver／gold nanoparticles；acrylamide；melamine V 万方数据 上海师范大学硕士学位论文 上海师范大学硕士学位论文 目录 目录 摘要．．．．．．．．．．．．．．． ．．．．．．．． ．．．． ．．．．． ．．．．．． ．．．．．．．．I Abstract．．．．．．．．．．．． ．．．．． ．．．．．．． ．．．．．． ．．．．．．． ．．．．．．．III 目录．．．．．．． ．．．．． ．．． ．．．．．． ．． ．．． ．V 第一章绪论 ．．．． ．．．．．． ．．．．．．．． ．．．．．．．．．．．．．．．．．．．．．．．．．．17 1．1拉曼光谱概述． ． ． ． ．． ．．． ．．．． ． ．．．．1 1．2拉曼散射的类型．．．．．．．．．．．．． ．．． ．．．．．．． ．．．．．．．．2 1．3表面增强拉曼散射光谱． ． ．．4 1．3．1表面增强拉曼光谱现象．． 4 1．3．2表面增强拉曼的基本原理 ．．．．． ．．．．． ．．． ．．．．． 4 1．3．3表面增强拉曼活性基底．． ． ．．． ．．6 1．4表面增强拉曼散射光谱的应用． ． ．．．．． ．．．．．10 1．4．1食品安全．．．． ．．．．． ．．．．． ．．10 1．4．2环境检测 ． ．．．． ．．． ． ． ． ．．，．．10 1．4．3生物医学应用 ．．．．． ．．． ．，．．．．．．． ．10 1．4．4表面吸附及催化反应 ．．．．．．． ． ．11 1．4．5与其他技术的联用