聚集诱导发光在化学发光分析及胶束形成过程监测中的应用-化学专业论文.docxVIP

优秀毕业论文 精品参考文献资料 北京化工大学硕士学位论文子、阳离子和非离子型表面活性剂在形成胶束过程中预胶束的存在，并可 北京化工大学硕士学位论文 子、阳离子和非离子型表面活性剂在形成胶束过程中预胶束的存在，并可 测量表面活性剂的临界胶束浓度(CMC)。本文第一次提出以AIE性质 的表面活性剂为探针监测胶束的形成过程，为解释胶束的形成机理和 CMC值测定提供了新的理论依据和方法。 关键词：聚集诱导发光，化学发光共振能量转移，预胶束，临界胶束浓度 万方数据 ABsTRACTTHE ABsTRACT THE APPLICATIoN FOR AGGREGATION INDUCED EMISSION ON CHEMILUMINESCENCE AN’D DETECTION OF MICELLE FORM【ATION PRoCESS AB STRACT The emergence of aggregation—induced emission(AlE)has opened up a new avenue for scientists．Compared with the conventional fluorescent dyes， AIE effect can boost the fluorescent intensities and fluorescent quantum yields when aggregated in concentrated solutions．The emergence of ME can sweep away the shortcomings of aggregation caused quenching(ACQ)．To date，a variety of fluorogens with AlE characteristics have attracted widespread interest as a multifunctional platform for various applications in chemical sensors，biological imaging，and optoelectronic devices．Therefore，we investigated the influence of AlE on the chemiluminescence(CL)emissions and the detection of micelle formation．The main research content iS as follows： (1)We selected gold nanoclusters，Au(I)-thiolate complexes and 9，1 0一bis[4一(3一sulfonatopropoxyl)-styryl]-anthracene(BSPSA)as model AlE molecules to reveal the role of AIE molecules on the bis(2，4，6-trichlorophenyl) oxalate(TCPO)一H202 CL system．It is found that these AlE molecules with an 万方数据 万方数据 万方数据 北京化工大学硕士学位论文increase 北京化工大学硕士学位论文 increase in the degree of aggregation exhibit remarkably enhanced performances toward the CL signals of the TCPO-H202 system．To gain further insight into AIE structure-property relationships in chemiluminescence resonance energy transfer(CRET)behavior,we have comprehensively explored the structural，optical，and CL properties．With respect to the experimental observations，we concluded unambiguously that the common natures of these AlE molecules are pivotal to improve the current CRET efficiency．Our SUCCESS should inspire more exciting research in the de