聚天冬氨酸与镁离子复合调控碳酸钙沉淀过程研究-环境科学专业论文.docxVIP

优秀毕业论文 精品参考文献资料 AbstractAbstract Abstract Abstract Special morphology and particle size are the principal elements that influence industrial properties of calcium carbonate material．Biomimetic synthesis is an effective way to prepare novel materials of calcium carbonate．Vaterite was formed effectively via regulating by Polyaspartic acid(PASP)，and magnesium is the classic revulsant of aragonite．PASP and magnesium ions are harmless and environmental friendly regulating agent．In this paper,the biomimetic mineralization process of calcium carbonate was studied by useing PASP and Mg肘as composite system．The optimum conditions of PASP and M92+system were determined．The structure and characterization of particles were analyzed by using FT-IR，XRD and SEM．The influence of reaction conditions on polymorphs，morphology and size of calcium carbonate were researched．The synthetic methods of the small size calcite sphere and aragonite sphere calcium carbonate were obtained．The formation and growth mechanisms ofthe crystal were analyzed based on the principles of biominerallization． (1)The vaterite content of calcium carbonate reached 90．52％when concentration of PASP was 2．5 mg／mL．In the system which concentration of PASP was 2．5 m【∥mL， since the mole concentration ratio of calcium and magnesium ions(M92+／Ca2、 enlarged from 0．01 to O．09．calcite content increased from 4．38％to 45．41％．As Mg肘 ／Ca付en larged from 0．1 to 2．2，calcite crystallinity decreased，and the morphology transformed from cubic rhombohedron with edges and corners adsorbed by tiny particles to sphere，diameter from 6．5 microns reduced to 1 micron．Elevating temperature was beneficial to the formation of calcite，morphology transformed from the round—likely roundness to sphere．Reaction time extended from 1 0 min to 40 min， morphology of calcium carbonate transfot’reed from cubic rhombohedron with steps to regu lar sphere． (2)When M92+／Ca2+reached 2，crystal content reached 9 1．20％，needle．1ike aragonite morphology was g