锂离子电池正极材料球形磷酸亚铁锂的研究-化学工程与技术专业论文.docxVIP

优秀毕业论文 精品参考文献资料 哈尔滨工 哈尔滨工业大学工学硕士学位论文 A bstract Olivine-type LiFePO 4 is considered as the m ost prom ising candidate forthe next generation cathode m aterials of lithium ion batteries because it has high theoreticalspecific capacity,is cheap and environm entally friendly,also has good cycling characteristics and excellent safety. H ow ever, it’s poor electronic conductivity, w hich leads to initial capacity loss and poor rate capability. A nd it’s low pile density, w hich leads to low volum etric specific capacity. That preventLiFePO 4to be putinto com m ercially used. In this w ork,w e aim at preparing spherical LiFePO 4.U sed liquid deposit- high tem perature sinter m ethod to synthesis sphericalL iFePO 4.Researched the influence of synthesis condition to N H 4FePO 4·H 2O precursor and LiFePO4 productin structure,pattern and electrochem icalperform ance.In addition,X -R ay D iffraction (X R D ) w as used to analyze the crystal structure of precursor and product, Scanning Electron M icroscope (SE M ) w as used to observe the superficial m orphology, charge-discharge test w as used to study the specific capacity and cyclic properties,C yclic Voltam m ogram (C V ) and E lectrochem ical Im pedance Spectroscope (E IS) w as used to discuss the electrochem ical reactive m echanism . The results ofthe study show thatuse FeSO 4·7H 2O ,H 3PO 4and N H 3·H 2O as m aterials to prepare N H 4FePO 4·H 2O precursor,the structure ofthe precursorand LiFePO 4 are sim ilarity, it is an effect of “structure preset”before sinter. C arbon doping can influence the tap density greatly, w ith the increase of carbon contentthe tap density decrease.The tap density is 1.28 g·cm -3,w hen doped w ith 5 m ass% carbon content. U sing LiF as lithium source,sucrose as carbon source, carbon content is 10 m ass% , 550 ℃ sinter for 12 h to prepare LiFePO 4,the sam ple has a discharge specific capacity of 120 m A h·g-1(0.1 C). The discharge specific capacity of nickeldoping sam ple