多壁碳纳米管的表面改性及其与环氧树脂复合研究材料学专业论文.docxVIP

多壁碳纳米管的表面改件及】e’j环瓴树脂复合研究摘 多壁碳纳米管的表面改件及】e’j环瓴树脂复合研究 摘 要 多壁碳纳米管(MWCNTs)独特的结构特点赋予了其优异的性能，自发现以来 倍受研究者的关注，有望成为先进复合材料的理想增强体。然而，原始MWCNTs 一方面因其易缠绕、团聚，使其在聚合物基体中难以分散均匀，另一方面，因表 面呈化学惰性，使其难以与基体材料形成强的界面结合力，从而限制了其应用范 围。功能化是解决这两个问题的有效途径，现已成为近年来的研究热点。本研究 在对MWCNTs进行氧化的基础上，利用硅烷偶联剂对其进行进一步功能化处理， 选择环氧树脂(Ep)作为基体材料，功能化后的MWCNTs为增强体，采用溶液共混 法制备了碳纳米管／环氧树脂纳米复合材料，研究了MWCNTs对复合材料力学、 热性能以及电性能的影响。 首先，通过采用三种氧化体系(H2S04／H202，H2S04／K2Cr207，H2S04／HN03) 对原始MWCNTs进行氧化处理的比较，发现采用H2SOd HN03体系所获得的产物 的综合效果最佳，MWCNTs的管状结构未见明显破坏。在此基础上，采用硅烷偶 联剂对其进行表面改性，采用红外光谱、拉曼光谱、热失重、Zeta电位激光粒度 分析仪、场发射扫描电镜、能量散射谱分析仪以及透射电镜对表面改性的样品进 行了表征，研究结果显示氧化MWCNTs表面接上硅烷分子，氧化MWCNTs与改性 后MWCNTs样品均能在水相中形成稳定的分散。 其次，采用溶液共混法制备了MWCNTs／Ep(AG80)基复合材料，考察改性后 MWCNTs不同含量对复合材料力学性能、热学性能以及导电性能的影响，研究结 果表明，与未处理碳管相比功能化MWCNTs在AG80基体树脂中分散效果和界面 作用得到显著增强，复合材料的力学性能和导电性显著提高，并保持较好的热稳 定性；当添加量达到0．75wt％时综合力学性能最佳。 关键词：多壁碳纳米管；环氧树脂；硅烷偶联剂；功能化；复合材料；溶液共混 Il 硕l：学位论丈Abstract 硕l：学位论丈 Abstract Multi．walled carbon nanotubes(MWCNTs)exhibit excellent performances due to their unique structures．which can be considered as an ideal reinforcement additive for advanced composites．However．unfunctional ized MWCNTs are chemicalinertia and exhibit weak interfacial interactions with resin matrix，which become most serious impediments during developing its researches and applications．The functionalization of MWCNTs iS an effective method to solve those problems，which has attracted more and more attentions in recent years．In this paper，MWCNTs were oxidated by acidic solution firstly，then treated by silane coupling agents in order to improve their chemical activity and solubility．Subsequently，the functionalized MWCNTs based on silanization reaction were added into Epoxy resin(Ep)using as the reinforcement． Finally，MWCNTs／Epoxy resin composites with different MWCNTs contents were prepared by solution blend．The mechanical，thermal and electronic properties of modified composites were investigated． Firstly，MWCNTs were functionalized using three kinds of oxidation system (H2S04／H202，H2S04／K2Cr207，H2S04／HN0