氧化铋和碳酸氧铋光催化剂的改性研究物理化学专业论文.docxVIP

PHOTOCATA PHOTOCATA L．YTIC ACTIVITY IMPRoVEMENT STUDIES FOR BISMUTH OXIDE AND BISMUTH OXYCARBONATE ABSTRACT Photocatalysis has eme玛ed as a promising technique owing to its valuable applications in environmental purification．The preparation of high efficient visible light responsed photocatalysts has attracted more and more attentions．In this work,Cu20-modified Bi203 nanospheres and Er-doped Bi202C03 microspheres with perfect visible—light catalytic activity were successfully synthesized．The obtained products were characterized by X—ray diffraction (XRD)， field emission scanning electron microscopy (FESEM) Brunauer-Emmett-Teller(BET)surface area，UV-visible diffuse reflectance spectroscopy(UV-vis DRS)，X—ray photoelectron spectroscopy(xPs)， transmission electron microscopy(TEM)，and X-ray fluorescence spectroscopy (XRF)．The photocatalytic activities were evaluated by degradation of Rhodamine B(RhB)． The prepared Cu20-modified Bi203 nanospheres exhibited enhanced photocatalytic activity in the degradation of RhB．Cu20 was dispersed on the surface of Bi203 nanospheres．All of Cu20一modified Bi203 nanospheres showed uniformly nanospheres with the size of 80-1 5 0 nm．Cu20 modification increased the BET surface area，narrowed band gap，and enlarged the light absorption II 万方数据 region．The region．The possible photocatalysis mechanism was the interfacial charge transfer process．This process accelerated the separation of photo-induced electron and holes，which leaded to the higher efficiency of photocatalysis． The prepared Er-doped Bi202C03 microspheres also showed enhanced photocatalytic activity in the degradation of RhB．In the prepared samples，Bi3+ was substituted by Er3+，which induced the decrease of lattice spacing．The higher BET surface area，the band gap narrowing and the broadened light absorption region was also caused by the doping of Er3+．In the photocatalysis， the host Bi202C03 could use visible light directly by virtue of the upconversion luminescent Er3+to generate hole