分子筛scr催化剂降低柴油机nox反应机理的数值模拟动力机械及工程专业论文.docxVIP

分子筛SCR催化剂降低柴油机NO。反应机理的数值模拟Numerical 分子筛SCR催化剂降低柴油机NO。反应机理的数值模拟 Numerical Simulation of Reaction Mechanism for Diesel NOx Reduction over Zeolite SCR Catalyst Abstract NOx emission from diesel engines iS one of the contributors for air pollution．Vehicles emission regulations，which are becoming more and more stringent，have promoted the development and application of NOx emission control technologies for diesel engines．Many engine and aftertreatment technologies have been put forward to reduce the NOx emission of diesel engines，and one of the most promising aftertreatment technologies is Selective Catalytic Reduction(SCR)．How to broaden the working temperature window of SCR and improve its NOx conversion at low and high temperature has always been concerned by researchers． Deeper understanding of NOx reduction process over catalyst is the precondition to improve the NOx conversion of SCR system．One dimensional global kinetics models were developed over Cu．and Fe．zeolite catalysts which have been widely used in urea-SCR aftertreatment technologies．NH3 adsorption／desorption，NHs oxidation，NO oxidation and NOx conversion reactions were taken into account in these models．These models were calibrated with experiments，and results show that the developed models satisfactorily predict the trends of species concentrations and conversion．A comparative study of the performance of Cu．and Fe-zeolite catalysts was carried out based on the calibrated models and results show that Cu—zeolite catalyst has a higher NH3 storage capacity and is more active in NH3 oxidation reaction．while Cu．and Fe．zeolite catalysts have comparable NO oxidation capacities．讹e11 the temperature iS below 400℃，Cu-zeolite catalyst iS more active in standard SCR reaction while the Fe-zeolite catalyst exhibits higher NOx conversion at higher temperatures．The influence of inlet N02／NOx ratio on NOx conversion Was investigated and found that Fe．zeolite catalyst is more sensitive to NOz／NOx feed ratio． Transient respo