润滑油加氢预处理催化剂的比选及工艺优化研究-应用科技.PDFVIP

第 45 卷第 3 期 应 用 科 技 Vol.45 No.3 2018 年 6 月 Applied Science and Technology Jun. 2018 DOI: 10.11991/yykj.201705013 网络出版地址：/kcms/detail/23.1191.U1617.004.html 润滑油加氢预处理催化剂的比选及工艺优化研究 王新苗，杨晓东，高善彬，马守涛 中国石油大庆化工研究中心，黑龙江 大庆 163714 摘 要：以大庆石蜡基200SN 酮苯脱蜡油为原料，开展了加氢精制与加氢裂化组合催化剂以及加氢精制催化剂之间的对比 评价，为炼厂润滑油加氢预处理催化剂的选择和工艺条件优化提供指导。结果表明，在相同的工艺条件下2 组催化剂加氢 脱杂质性能和改善黏指性能相近，但组合催化剂润滑油馏分收率损失较大；采用HDT-0 1 加氢精制催化剂，在体积空速 1.45 h-1、反应温度385 ℃、氢气分压 13.5 MPa、氢油体积比800:1 的条件下，大于400 ℃润滑油馏分产品的硫含量1.0 μg/g，氮 含量1.0 μg/g，黏指 116，收率77%，可高收率获得异构段原料。 关键词：200SN 酮苯脱蜡油；加氢预处理；加氢裂化；催化剂；润滑油基础油；加氢脱硫；加氢脱氮；黏指 中图分类号：TE622.1 文献标志码：A 文章编号：1009−671X(2018)03−0092−04 Comparison and process optimization of hydrotreating catalyst for lubricant base oil WANG Xinmiao, YANG Xiaodong, GAO Shanbin, MA Shoutao Daqing Petrochemical Research Center, CNPC, Daqing 163714, China Abstract: Using the paraffin base 200SN benzol-ketone dewaxing oil produced in Daqing as feedstock, a comparative evaluation of the hydrotreating catalysts combined with the hydrocracking catalyst and the hydrotreating catalyst was carried out respectively, providing a guidance to the selection of lubricant oil hydrotreating catalysts and process condition optimization for refinery. The results showed that under the same reaction conditions, the hydrodesulfurization and hydrodenitrogen performance and the viscosity index increment performance of two groups of catalysts was equivalent, but the loss of lube distillate yield was larger when using the combined catalysts. The results showed under